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The Transition from Quantity to Quality: The Exploration and Reform on the International Training Scheme for Top Chemistry Undergraduate Students at the Stage of “Top-notch Undergraduate Training Program 2.0” 从数量到质量的转变"拔尖本科生培养计划2.0 "阶段化学拔尖本科生国际培养计划的探索与改革
Pub Date : 2020-03-19 DOI: 10.3866/PKU.DXHX202002015
Xiaoshuang Ma, Chengbin Zheng
: Since 2009 when Sichuan University started to implement the Top-notch Undergraduate Training Program (Top-notch Program for short) in Chemistry, a relatively comprehensive scheme of international training has been established and progress has been made. As the Ministry of Education starts the “Top-notch Undergraduate Training Program 2.0” in 2019, we are obliged to review the current international training model for chemistry undergraduates by learning from other universities both domestic and overseas to explore better ways of deepening international cooperation and improving the quality of international training for top chemistry students.
:四川大学化学学科自2009年开始实施 "拔尖本科生培养计划"(简称 "拔尖计划")以来,已经形成了较为完善的国际化培养方案,并取得了一定的进展。随着2019年教育部启动 "2.0版拔尖本科生培养计划",我们有责任通过向国内外其他高校学习,重新审视目前的化学本科生国际培养模式,探索深化国际合作、提高化学拔尖学生国际培养质量的更好途径。
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引用次数: 0
Preparation, Characterization and Catalytic Transesterification Performance of KF/La2O2CO3 as Solid Base Catalyst: A Comprehensive Innovation Experiment KF/La2O2CO3固体碱催化剂的制备、表征及催化酯交换性能:综合创新实验
Pub Date : 2020-02-13 DOI: 10.3866/pku.dxhx201912008
Ni Xiaoyu, Li Zhibin, Wang Kai, Fan Yaling, Chen Jing, Zhu Yujun
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引用次数: 0
Macroscopic Morphology of Alum(K) Crystal 明矾(K)晶体的宏观形貌
Pub Date : 2020-01-01 DOI: 10.3866/pku.dxhx201904013
Tianyi Zhang, Yu-ChingE. Pan, Yihan Xu, Aili Cui
: In this paper, a simple thermodynamic model of crystal macroscopic morphology and the cause of the defects were suggested. By virtue of growing alum(K) crystals and measuring their macroscopic parameters in the inorganic laboratory for undergraduates, we can calculate the thermodynamic parameters of alum, thus explaining the macroscopic morphology and defect of alum(K), and predicting the possibility for alum(K) to generate octahedral crystals and its self-normality.
本文提出了晶体宏观形貌的简单热力学模型及缺陷产生的原因。通过在本科生无机实验室中生长明矾(K)晶体并测量其宏观参数,可以计算出明矾的热力学参数,从而解释明矾(K)的宏观形貌和缺陷,预测明矾(K)生成八面体晶体及其自正态性的可能性。
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引用次数: 0
A Comprehensive Chemical Experiment on Synthesis and Thermal Stability Study of Hybrid Perovskite Photovoltaic Materials 杂化钙钛矿光伏材料合成及热稳定性综合化学实验研究
Pub Date : 2020-01-01 DOI: 10.3866/pku.dxhx201904004
P. Che, Han Yang, Huili Fan, Ming-wen Wang, Wenjun Li
: In this paper, a comprehensive chemical experiment is introduced, including the preparation of organic-inorganic hybrid perovskite photovoltaic materials by one-step solution method. The characterization of crystal structure and morphology, the test of UV-Vis absorption spectrum, and the study of thermal stability of the obtained materials were carried out.
本文介绍了一种综合化学实验,包括一步溶液法制备有机-无机杂化钙钛矿光伏材料。对所得材料进行了晶体结构和形貌表征、紫外-可见吸收光谱测试和热稳定性研究。
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引用次数: 0
Testing the Buffer Capacity of Baby Wipes: An Experiment Close to Life 测试婴儿湿巾的缓冲能力:一个接近生活的实验
Pub Date : 2020-01-01 DOI: 10.3866/pku.dxhx201905022
F. Yu, 光电化学材料与器件教育部重点实验室 武汉 sup 江汉大学化学与环境工程学院, Bao Li, 武汉 sup 华中科技大学化学与化工学院
: In order to effectively enhance students’ interest and enthusiasm in learning buffer solution, a case of introducing real daily necessities into laboratory teaching is recommended. The experimental design extends the property test to the baby wipe, and changes the content of the experiment into the verification of the working principle of wipe, instead of preparation of simple acid-base system and related verification experiments in the past. Through the implementation of this experiment, students generally reflected that it can effectively stimulate their enthusiasm and interest in learning buffer solution related contents, and ultimately promote them to recognize the characteristics and buffer mechanism of pH changes in buffer system.
:为有效提高学生学习缓冲溶液的兴趣和热情,推荐一个将真实生活用品引入实验教学的案例。本实验设计将性能测试扩展到婴儿湿巾,将实验内容改为对湿巾工作原理的验证,而不是以往简单的酸碱体系制备及相关验证实验。通过本实验的实施,学生普遍反映可以有效激发他们学习缓冲液相关内容的积极性和兴趣,最终促进他们认识缓冲体系pH变化的特点和缓冲机制。
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引用次数: 0
Synthesis and Characterization of a Fluorescent Probe Based on Schiff-Base 席夫碱荧光探针的合成与表征
Pub Date : 2020-01-01 DOI: 10.3866/pku.dxhx201906008
Changyan Sun, Wenjun Li, Hui-li Lu
: In this paper, a new experiment named “synthesis and characterization of a fluorescent molecule based on Schiff-base” is introduced. It contains the synthesis and characterization of organic compounds, the determination of fluorescence, and the detection of metal ions. This experiment is helpful for students to better understand inorganic chemistry, organic chemistry and analytical chemistry. Moreover, it gives students an opportunity to know the study of organic fluorescent probes. This will stimulate students’ interest in scientific research and cultivate their research ability. Thus, this experiment can be introduced to senior undergraduates.
本文介绍了一个新实验——“基于席夫碱的荧光分子的合成与表征”。它包含有机化合物的合成和表征,荧光的测定,以及金属离子的检测。本实验有助于学生更好地理解无机化学、有机化学和分析化学。此外,它给学生一个机会了解有机荧光探针的研究。这将激发学生的科研兴趣,培养他们的科研能力。因此,本实验可以介绍给高年级本科生。
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引用次数: 0
Better Understanding Theoretical Knowledge through Laboratory Teaching: Taking "Gas Chromatography Experiment" as an Example 通过实验教学加深对理论知识的理解——以“气相色谱实验”为例
Pub Date : 2020-01-01 DOI: 10.3866/pku.dxhx201906063
Junhong Qian, P. Hu, Lei Zhou, Wenqing Zhang, D. Zou, Yan Wang
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引用次数: 0
Synthesis and Structural Characterization of Two Types of Chromene Derivatives Containing Pyrazolone or Indol-2-one: Reaction and Chemoselectivity of Carbonyl and Aldehyde Groups 两类含吡唑酮或吲哚-2-酮的铬胺衍生物的合成及结构表征:羰基和醛基的反应及化学选择性
Pub Date : 2020-01-01 DOI: 10.3866/pku.dxhx201907004
Xuange Zhang, Tianyu Lu, Yan Cai, Zihong Yan, Zhiwei Miao
: Under the catalytic conditions of tetrahydropyrrole, an addition-elimination reaction of chromone aldehyde with methylpyrazolone or 2-indolinone is carried out to obtain two kinds of chromene derivatives containing pyrazolone or indol-2-one. The structures are identified by 1 H NMR, 13 C NMR, HPLC, HRMS and melting point measurements.
:在四氢吡咯的催化条件下,铬醛与甲基吡唑啉酮或2-吲哚啉酮进行加消反应,得到两种含吡唑啉酮或吲哚-2-酮的铬衍生物。通过1h NMR, 13c NMR, HPLC, HRMS和熔点测量对其结构进行了鉴定。
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引用次数: 0
Guided Solution to the 33th Chinese Chemistry Olympiad (Preliminary Test) 第33届中国化学奥林匹克竞赛(初试)指导解答
Pub Date : 2020-01-01 DOI: 10.3866/pku.dxhx201910066
Hanyun Liu
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引用次数: 0
A Taste of Chemistry: The Alcohol’s Biography 《化学的味道:酒精的传记
Pub Date : 2020-01-01 DOI: 10.3866/pku.dxhx202002014
Y. Gong, S. Hongjie, Lichun Zhang
: Greatness of clear wine comes from wooden ploughs. As an indispensable part of Chinese food culture, wine has gone through thousands of years with us. This essay will make an introduction of aspects of ethanol’s nature, origin, metabolism by means of personification and in form of how Alcohol pursues his own memories, aiming at making readers feel the taste of chemistry with the popularization of science integrating science and fun.
伟大的清酒来自木犁。酒作为中国饮食文化不可或缺的一部分,伴随我们走过了几千年。本文将通过拟人化的方式,以Alcohol如何追求自己的记忆为形式,对乙醇的性质、起源、代谢等方面进行介绍,以科学与趣味相结合的科普方式,让读者感受到化学的味道。
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引用次数: 0
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