Analysis of the Temperature Deviation for Boiling of Liquid and Condensation of Vapor Using Kelvin Equation

Z. Tao, Shuyong Zhang
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Abstract

: The discrepancies for calculating condensation temperature and boiling temperature for droplet and small bubble using Kelvin equation were discussed. The discrepancies can be ascribed to the neglect of variation of the vapor pressure of curved surface to plain surface with temperature, and the misusing of Kelvin equation for small bubble during boiling. The way to reduce the discrepancy is introduced while the applicability of Kelvin equation is discussed.
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用开尔文方程分析液体沸腾和蒸汽冷凝的温度偏差
讨论了用开尔文方程计算液滴和小气泡的冷凝温度和沸腾温度的差异。这种差异可归因于忽略了曲面与平面的蒸气压随温度的变化,以及小气泡沸腾过程中开尔文方程的误用。介绍了减小误差的方法,并讨论了开尔文方程的适用性。
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