{"title":"Positive-ion mass spectra of some polychloro-organomercurials","authors":"S. C. Cohen","doi":"10.1039/J19710000632","DOIUrl":null,"url":null,"abstract":"The mass spectra of bis(pentachlorophenyl)mercury, pentachlorophenylmercury(II) chloride, bis(trichlorovinyl)-mercury, and trichlorovinylmercury(II) chloride yield (R – Cl)+ as the most intense organo-ion. This is explained, by use of clastograms and relative appearance potentials, as being due to the preferential elimination of HgCl2 rather than Hg–C bond cleavage, RHgX+ [graphic omitted] RHg+ [graphic omitted] R+(X = R or Cl).","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710000632","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 4
Abstract
The mass spectra of bis(pentachlorophenyl)mercury, pentachlorophenylmercury(II) chloride, bis(trichlorovinyl)-mercury, and trichlorovinylmercury(II) chloride yield (R – Cl)+ as the most intense organo-ion. This is explained, by use of clastograms and relative appearance potentials, as being due to the preferential elimination of HgCl2 rather than Hg–C bond cleavage, RHgX+ [graphic omitted] RHg+ [graphic omitted] R+(X = R or Cl).
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