{"title":"Single-crystal electronic and electron spin resonance spectra of bis(ethoxyacetato)bisaquocopper(II)","authors":"R. J. Fereday, B. Hathaway","doi":"10.1039/J19710002758","DOIUrl":null,"url":null,"abstract":"The polarised single-crystal electronic and e.s.r. spectra of bis(ethoxyacetato)bisaquocopper(II) have been measured. The correlation of the single-crystal g-values and the crystallographic data suggest a dx2–y2 ground-state for the CuO4O′2 chromophore. The polarised single-crystal electronic spectra are interpreted in the effective symmetry of D2h and yield the tentative partial one-electron orbital sequence dx2–y2 > dz2 > dyz > dxz.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":"4 1","pages":"2758-2761"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710002758","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
Abstract
The polarised single-crystal electronic and e.s.r. spectra of bis(ethoxyacetato)bisaquocopper(II) have been measured. The correlation of the single-crystal g-values and the crystallographic data suggest a dx2–y2 ground-state for the CuO4O′2 chromophore. The polarised single-crystal electronic spectra are interpreted in the effective symmetry of D2h and yield the tentative partial one-electron orbital sequence dx2–y2 > dz2 > dyz > dxz.
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