Single-crystal electronic and electron spin resonance spectra of bis(ethoxyacetato)bisaquocopper(II)

R. J. Fereday, B. Hathaway
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引用次数: 1

Abstract

The polarised single-crystal electronic and e.s.r. spectra of bis(ethoxyacetato)bisaquocopper(II) have been measured. The correlation of the single-crystal g-values and the crystallographic data suggest a dx2–y2 ground-state for the CuO4O′2 chromophore. The polarised single-crystal electronic spectra are interpreted in the effective symmetry of D2h and yield the tentative partial one-electron orbital sequence dx2–y2 > dz2 > dyz > dxz.
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双(乙氧基乙酸酯)双铜(II)的单晶电子和电子自旋共振谱
测定了双(乙氧基乙酸酯)双水铜(II)的极化单晶电子谱和电磁共振谱。单晶g值与晶体学数据的相关性表明,cuo40o ' 2的基态为dx2-y2。用D2h的有效对称解释了极化单晶电子能谱,得到了dx2-y2 > dz2 > dyz > dxz的部分单电子轨道序列。
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