Study on synthesis and characterization of electrocatalyst containing platinum on graphite electrode for hydrogen evolution reaction

H. Nguyen, T. Nguyen, Thuc Van Nguyen
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Abstract

In this study, we have successfully synthesized electrode materials containing Pt on modified graphite by electrodeposition method, such as: Pt/C, Pt-Au/C Pt-Pd/C, Pt-Ni/C, Pt-Ni-Au/C, Pt-Ni-Pd/C. The formation of materials coating on the modified graphite surface is demonstrated through SEM, EDS results. Synthetic materials are used as catalysts for hydrogen evolution reaction (HER). The results show that Bimetallic composites containing Pt exhibit higher catalytic activity than the monometallic material Pt/C. Trimetallic materials Pt-Ni-Au/C and Pt-Ni-Pd/C have catalytic activity for HER insignificant lower than that of Pt-Au/C and Pt-Pd/C electrodes.  However, the precious metal composition in the trimetallic composite material system is reduced, which is also an important goal of research and opens up prospects for the fabrication of next-generation composite materials systems.
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石墨电极含铂析氢电催化剂的合成及表征研究
本研究通过电沉积法在改性石墨上成功合成了Pt/C、Pt- au /C、Pt- pd /C、Pt- ni /C、Pt- ni - au /C、Pt- ni - pd /C等含Pt的电极材料。通过扫描电镜(SEM)、能谱分析(EDS)等结果表明,改性后的石墨表面形成了涂层。合成材料作为析氢反应的催化剂。结果表明,含Pt的双金属复合材料比单金属材料Pt/C具有更高的催化活性。三金属材料Pt-Ni-Au/C和Pt-Ni-Pd/C对HER的催化活性不显著低于Pt-Au/C和Pt-Pd/C电极。然而,三金属复合材料体系中的贵金属成分减少,这也是研究的一个重要目标,为下一代复合材料体系的制造开辟了前景。
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