Influence of Prolonged Annealing on Properties of Y2O3 Nanosized Ceramics

O. Kalantaryan, S. Kononenko, E. Barannik, V. Zhurenko, V. Chishkala
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引用次数: 3

Abstract

The paper deals with the influence of sintering and annealing on the luminescence spectra of yttrium oxide nanosized ceramics. We pressed commercial yttrium oxide nanopowder to pellets with subsequent sintering at 1500 °C for 1 hour in air. Some samples were additionally annealed at 1000°C for 10 hours. XRD and SEM analysis of the ceramics pointed out that both types of the samples did not differ in crystal structure. A comparison of the luminescence spectra showed some differences in the first (maximum near 350 nm) and the third wavelength bands (maximum near 455 nm). The phonon energies increasing in the ground exciton state caused by stiffening of the lattice may be responsible for the annealing dependent properties at the first spectral band.
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长时间退火对Y2O3纳米陶瓷性能的影响
研究了烧结和退火对氧化钇纳米陶瓷发光光谱的影响。我们将商用氧化钇纳米粉压成颗粒,随后在空气中1500℃烧结1小时。一些样品在1000℃下额外退火10小时。XRD和SEM分析表明,两种样品的晶体结构没有差异。发光光谱的比较表明,第一波段(最大波长在350 nm附近)和第三波段(最大波长在455nm附近)存在一定的差异。晶格硬化引起的基态激子能量的增加可能是第一光谱带退火相关性质的原因。
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