Plasma Treatment of Carbon Nanofibers Using an Anode Layer Ion Source for High-Performance Electrochemical Capacitors

Yu-jin Lee, Do‐Geun Kim, H. Ahn
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引用次数: 1

Abstract

We synthesized carbon nanofibers(CNFs) by electrospinning and then activated their surface states via plasma treatment with an anode layer ion source. We studied the effects of various treatment times—0, 400, 800, and 1200 seconds—in order to identify the optimum conditions for plasma treatment. We investigated the morphological and structural properties, and the chemical composition of the CNFs using scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy. The activated CNFs—plasma-treated for 1200s—exhibited excellent capacitance(∼173.25 F/g at 5 mV/s), superb cycling stability(∼92.59%), and the highest energy density(∼6.81 Wh/kg) among the different samples produced.
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用阳极层离子源等离子体处理高性能电化学电容器用纳米碳纤维
采用静电纺丝法合成了碳纳米纤维(CNFs),并通过阳极层离子源等离子体处理激活了其表面态。我们研究了不同处理时间(0,400,800和1200秒)的效果,以确定等离子体处理的最佳条件。利用扫描电镜、透射电镜、拉曼光谱、傅立叶变换红外光谱和x射线光电子能谱等研究了CNFs的形态、结构和化学成分。活化的cnfs -等离子体处理1200秒-表现出优异的电容(5 mV/s下~ 173.25 F/g),极好的循环稳定性(~ 92.59%)和不同样品中最高的能量密度(~ 6.81 Wh/kg)。
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来源期刊
ECS Solid State Letters
ECS Solid State Letters MATERIALS SCIENCE, MULTIDISCIPLINARY-PHYSICS, APPLIED
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