Metal carbonyl chemistry. Part XV. Reactions of the dicarbonylbis-(triphenylphosphine)rhodate anion, [Rh(CO)2(PPh3)2]–, with some perfluoroaromatic compounds
{"title":"Metal carbonyl chemistry. Part XV. Reactions of the dicarbonylbis-(triphenylphosphine)rhodate anion, [Rh(CO)2(PPh3)2]–, with some perfluoroaromatic compounds","authors":"B. Booth, R. Haszeldine, Ian Perkins","doi":"10.1039/J19710000927","DOIUrl":null,"url":null,"abstract":"The carbonylmetal anion [Rh(CO)2(PPh3)2]– has been shown to be a strong nucleophile of similar power to that of [(π-C5H5)Fe(CO)2]– or [(π-C5H5)Ru(CO)2]–. Its reactions with the compounds C6F6, C6F5X (X = CN or CO2Et), (NC)2C6F4, C5F5N, and 2-(NC)C5F4N to afford some new perfluoroaromatic rhodium(l) complexes are discussed.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"6","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710000927","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 6
Abstract
The carbonylmetal anion [Rh(CO)2(PPh3)2]– has been shown to be a strong nucleophile of similar power to that of [(π-C5H5)Fe(CO)2]– or [(π-C5H5)Ru(CO)2]–. Its reactions with the compounds C6F6, C6F5X (X = CN or CO2Et), (NC)2C6F4, C5F5N, and 2-(NC)C5F4N to afford some new perfluoroaromatic rhodium(l) complexes are discussed.
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