Comparison between the volatile substances in spirits beverages distilled by two different initial materials of Prunus domestica “Stanley” in an industrial environment

Mariana Galabova, N. Stoyanov, P. Mitev
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Abstract

Analysis of the chemical composition of volatile substances in two distillates from Prunus domestica “Stanley” cultivated in the village of Rumyantsevo, Lovech, Bulgaria. Production is in an industrial environment, fermentation and distillation are carried out under equal conditions, but on different starting materials. One batch PDS-1 distilled from fermented mash and second batch PDS-2 distilled from fermented juice. The distillation apparatus is equipped with a rectifying column with 4 trays, as well as a water reflux condenser. Determination of congeners in both samples was done by gas chromatography principle OIV-MA-BS-14:2009. Methodology used for measuring alcohol content, cyanide derivatives, furfural and total acidity is according to the requirements of the OIV. In PDS-1 methanol (1094.7 g/hL a.a.) is almost 8% higher than in PDS-2 (1015.8 g/hL a.a.), it was found insignificant increase of furfural content in distillates of PDS-1 than in PDS-2. Concerning esters, aldehydes and higher alcohols the amount in PDS- 1 is significantly higher than in PDS-2, respectively 203.06 g/hL, 14.2 g/hL and 484.6 g/hL in batch fermented with hard particles, and 14.2 g/hL, 8.6 g/hL, 267.9 g/hL in batch produced from fermented juice.
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工业环境下两种不同原料家李蒸馏烈酒中挥发性物质的比较
保加利亚Lovech Rumyantsevo村栽培的两种李(Prunus domestica“Stanley”)蒸馏物中挥发性物质的化学成分分析。生产是在工业环境中进行的,发酵和蒸馏在相同的条件下进行,但在不同的起始材料上。第一批从发酵醪中蒸馏出PDS-1,第二批从发酵果汁中蒸馏出PDS-2。精馏装置配有4个塔板的精馏塔,以及一个水回流冷凝器。采用气相色谱法测定两种样品中的同源物。用于测量酒精含量、氰化物衍生物、糠醛和总酸度的方法符合国际标准的要求。PDS-1甲醇(a.a.a. 1094.7 g/hL)比PDS-2 (a.a.a. 1015.8 g/hL)高出近8%,但PDS-1馏分物中糠醛含量比PDS-2馏分物无明显提高。PDS- 1中酯类、醛类和高醇类的含量显著高于PDS-2,用硬颗粒分批发酵时酯类、醛类和高醇类的含量分别为203.06 g/hL、14.2 g/hL和484.6 g/hL,发酵液分批发酵时酯类、醛类和高醇类的含量分别为14.2 g/hL、8.6 g/hL和267.9 g/hL。
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