Aluminum Nano stars with localized surface plasmon resonance and field enhancement

J. Katyal, C. Sharma, R. Singh
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Abstract

The Finite Difference Time Domain approach has been used to assess the localised surface plasmon resonance and field enhancement for Al nanostars. The structure's potential as a refractive index sensor has been demonstrated. Research on plasmonics has been possible in a variety of domains, including sensors, SERS, solar cells, and others, due to a tenability in the plasmon wavelength caused by a simple change in shape, size, or external environment. The growth of plasmonics has been greatly aided by the creation of novel ways for creating metallic nanostructures and a large deal of work on the creation of numerical algorithms to cope with arbitrarily shaped metallic nanostructures. The LSPR and field enhancement of an Al nano-star were the main topics of this paper. A larger RIS factor is obtained after adjusting the refractive index sensitivity parameter, making it appropriate for refractive index-based sensor nanostructures. This study's primary goal is to provide a comparative analysis of the refractive index sensitivity factor for Al nanostars dependent on their size and number of arms. Al nano star's LSPR and field enhancement have been assessed using the Finite Difference Time Domain (FDTD). By altering the size and number of arms of the nano star, the tenability of the plasmonic peak has been assessed, and it has been found that the peak is sensitive to the ambient dielectric constant. A study has been done on the refractive index sensitivity parameter. A higher sensitivity of about 370 nm/RIU, which is significantly higher than that of other metallic Nanostar (NS), is seen after adjusting the size and number of arms. A wide range of applications is covered by the Al NS field enhancement pattern, which exhibits stronger enhancement with no aggregation at the plasmon peak. For LSPR sensing applications, the impact of modifying the environmental dielectric constant is examined. By changing the size and quantity of the Al NS's arms, we were able to compare the refractive index sensitivity parameter. The bigger size NS exhibits more peaks due to the contribution of the multipole; however, after tuning a number of parameters, better sensitivity in comparison to Au and Ag nanostar has been attained. Al NS can therefore be a promising sensing material for refractive index sensing employing LSPR properties.
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具有局域表面等离子体共振和场增强的铝纳米星
利用时域有限差分方法对铝纳米星的局部表面等离子体共振和场增强进行了研究。该结构作为折射率传感器的潜力已被证明。等离子体的研究已经在许多领域成为可能,包括传感器、SERS、太阳能电池和其他领域,这是由于形状、大小或外部环境的简单变化引起的等离子体波长的可维持性。创造金属纳米结构的新方法,以及创造处理任意形状金属纳米结构的数值算法的大量工作,极大地促进了等离子体动力学的发展。本文主要研究了Al纳米星的LSPR和场增强。调整折射率灵敏度参数后,获得了较大的RIS因子,使其适用于折射率传感器纳米结构。本研究的主要目的是对铝纳米星的折射率敏感系数与臂的大小和数量的关系进行比较分析。利用时域有限差分法(FDTD)对Al纳米星的LSPR和场增强进行了评价。通过改变纳米星臂的大小和数目,评估了等离子体峰值的可维持性,发现等离子体峰值对环境介电常数敏感。对折射率灵敏度参数进行了研究。调整臂的大小和数量后,纳米星的灵敏度可达370 nm/RIU左右,明显高于其他金属纳米星。Al - NS场增强模式具有较强的增强效应,且在等离子体峰处无聚集,具有广泛的应用前景。对于LSPR传感应用,研究了改变环境介电常数的影响。通过改变Al - NS臂的大小和数量,我们可以比较折射率灵敏度参数。尺寸越大,由于多极子的贡献,NS呈现出更多的峰;然而,在调整了一些参数之后,与Au和Ag纳米星相比,获得了更好的灵敏度。因此,Al - NS可以成为利用LSPR特性进行折射率传感的有前途的传感材料。
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来源期刊
Nanoscience and Nanotechnology - Asia
Nanoscience and Nanotechnology - Asia Engineering-Engineering (all)
CiteScore
1.90
自引率
0.00%
发文量
35
期刊介绍: Nanoscience & Nanotechnology-Asia publishes expert reviews, original research articles, letters and guest edited issues on all the most recent advances in nanoscience and nanotechnology with an emphasis on research in Asia and Japan. All aspects of the field are represented including chemistry, physics, materials science, biology and engineering mainly covering the following; synthesis, characterization, assembly, theory, and simulation of nanostructures (nanomaterials and assemblies, nanodevices, nano-bubbles, nano-droplets, nanofluidics, and self-assembled structures), nanofabrication, nanobiotechnology, nanomedicine and methods and tools for nanoscience and nanotechnology.
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