A study of fast pyrolysis of plant biomass assisted by the conversion of volatile products using Fe(Co, Ni)/ZSM-5 catalysts

Yu.V. Lugovoy, K. Chalov, Y. Kosivtsov, A. Stepacheva, E. Sulman
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Abstract

Abstract This paper discusses the study of plant waste thermocatalytic conversion. The dependence of the conversion of agricultural waste on the pyrolysis temperature, reaction time and feedstock particle size was determined. The optimal temperature of fast pyrolysis providing the highest yield of gaseous products (over 30 wt. %) for all types of waste plant biomass was found to be 700 ºC. This temperature allows the lowest tar content in gases to be obtained. Further, ZSM-5 synthetic zeolites modified with iron subgroup metals were studied in the conversion of volatile products obtained by the fast pyrolysis of agricultural waste. It was found that the use of zeolite-based catalysts in the upgrading of gaseous products leads to a decrease in tar content and the increase in the volume concentration of С1-С4 hydrocarbons, CO, CO2, and hydrogen in comparison with the non-catalytic process.
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Fe(Co, Ni)/ZSM-5催化剂催化植物生物质快速热解挥发性产物转化研究
摘要本文对植物废弃物热催化转化的研究进行了探讨。研究了热解温度、反应时间和原料粒度对农业废弃物转化率的影响。对于所有类型的废弃植物生物质,提供最高气态产物收率(超过30 wt. %)的最佳快速热解温度为700℃。这个温度可以使气体中的焦油含量达到最低。在此基础上,研究了铁亚族金属改性ZSM-5型合成沸石对农业废弃物快速热解挥发性产物的转化作用。研究发现,与非催化工艺相比,使用沸石基催化剂对气态产物进行升级,导致焦油含量降低,С1-С4碳氢化合物、CO、CO2和氢的体积浓度增加。
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