The role of defects in solar cells: Control and detection defects in solar cells

S. Dueñas, E. Perez, H. Castán, H. García, L. Bailón
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引用次数: 10

Abstract

The performance of commercial solar cells is strongly controlled by the impurities and defects present in the substrates. Defects induce deep energy levels in the semiconductor bandgap, which degrade the carrier lifetime and quantum efficiency of solar cells. A comprehensive knowledge of the properties of defects require electrical characterization techniques providing information about the defect concentration, spatial distribution and physical origin. The experimental techniques available in our laboratory are described in this work. In contrast, the efficiency of single junction solar cells can be drastically improved by the formation of an intermediate band in the midgap of a semiconductor. The intermediate band can be created from deep level defects if their concentration is high enough. Experimental results proving the intermediate band formation are also presented in this work.
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缺陷在太阳能电池中的作用:控制和检测太阳能电池中的缺陷
商用太阳能电池的性能在很大程度上受到衬底中存在的杂质和缺陷的控制。缺陷会在半导体带隙中产生深能级,从而降低太阳能电池的载流子寿命和量子效率。对缺陷特性的全面了解需要电表征技术来提供有关缺陷浓度、空间分布和物理起源的信息。本工作描述了我们实验室可用的实验技术。相比之下,单结太阳能电池的效率可以通过在半导体的中隙中形成中间带而大大提高。如果深能级缺陷的浓度足够高,则可以产生中间带。实验结果证明了中间带的形成。
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