The potential for hydrogen ironmaking in New Zealand

Cassidy van Vuuren , Ao Zhang , James T. Hinkley , Chris W. Bumby , Matthew J. Watson
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引用次数: 1

Abstract

Globally, iron and steel production is responsible for approximately 6.3% of global man-made carbon dioxide emissions, because coal is used as both the combustion fuel and chemical reductant. Hydrogen reduction of iron ore offers a potential alternative ‘near-zero-CO2’ route, if renewable electrical power is used for both hydrogen electrolysis and reactor heating. This paper discusses key technoeconomic considerations for establishing a hydrogen direct reduced iron (H2-DRI) plant in New Zealand. The location and availability of firm renewable electricity generation is described, the experimental feasibility of reducing locally-sourced titanomagnetite ironsand in hydrogen is shown, and a high-level process flow diagram for a counter-flow electrically heated H2-DRI process is developed. The minimum hydrogen composition of the reactor off-gas is 46%, necessitating the inclusion of a hydrogen recycle loop to maximise chemical utilisation of hydrogen and minimize costs. A total electrical energy requirement of 3.24 MWh per tonne of H2-DRI is obtained for the base-case process considered here. Overall, a maximum input electricity cost of no more than US$80 per MWh at the plant is required to be cost-competitive with existing carbothermic DRI processes. Production cost savings could be achieved through realistic future improvements in electrolyser efficiency (∼ US$5 per tonne of H2-DRI) and heat exchanger (∼US$3 per tonne). We conclude that commercial H2-DRI production in New Zealand is entirely feasible, but will ultimately depend upon the price paid for firm electrical power at the plant.

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新西兰氢炼铁的潜力
在全球范围内,钢铁生产约占全球人为二氧化碳排放量的6.3%,因为煤炭既被用作燃烧燃料,又被用作化学还原剂。如果将可再生电力用于氢电解和反应堆加热,铁矿石的氢还原提供了一种潜在的“接近零二氧化碳”的替代途径。本文讨论了在新西兰建立氢直接还原铁(H2-DRI)工厂的关键技术经济考虑因素。描述了企业可再生能源发电的位置和可用性,展示了在氢气中减少本地来源的钛磁铁矿铁砂的实验可行性,并开发了逆流电加热H2-DRI工艺的高级工艺流程图。反应器废气的最低氢成分为46%,因此需要包含氢回收循环,以最大限度地提高氢的化学利用率并最大限度地降低成本。在这里考虑的基本情况过程中,每吨H2-DRI的总电能需求为3.24兆瓦时。总的来说,工厂的最大输入电力成本不超过每兆瓦时80美元,才能与现有的碳热DRI工艺在成本上具有竞争力。生产成本的节约可以通过未来电解槽效率(每吨H2-DRI约5美元)和热交换器(每吨约3美元)的实际改进来实现。我们的结论是,H2-DRI在新西兰的商业化生产是完全可行的,但最终将取决于工厂为稳定电力支付的价格。
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