Jian-Yu Zheng, Shuichi Noguchi, Kenjo Miyauchi, Masahiro Hamada, K. Kinbara, K. Saigo
{"title":"TETHER-LINKED [60]FULLERENE-DONOR DYADS","authors":"Jian-Yu Zheng, Shuichi Noguchi, Kenjo Miyauchi, Masahiro Hamada, K. Kinbara, K. Saigo","doi":"10.1081/FST-100107149","DOIUrl":null,"url":null,"abstract":"A series of [60]fullerene bis-adducts having a π-electron-rich aromatic ring as a donor in a face-to-face arrangement were synthesized by the bis-cyclopropanation of [60]fullerene with tether-linked bis-malonates. One of the bis-adducts showed a photoinduced intramolecular electron transfer which caused the dramatic quenching of its fluorescence in a polar solvent.","PeriodicalId":12470,"journal":{"name":"Fullerene Science and Technology","volume":"342 1","pages":"467 - 475"},"PeriodicalIF":0.0000,"publicationDate":"2001-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Fullerene Science and Technology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1081/FST-100107149","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 2
Abstract
A series of [60]fullerene bis-adducts having a π-electron-rich aromatic ring as a donor in a face-to-face arrangement were synthesized by the bis-cyclopropanation of [60]fullerene with tether-linked bis-malonates. One of the bis-adducts showed a photoinduced intramolecular electron transfer which caused the dramatic quenching of its fluorescence in a polar solvent.
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