{"title":"Investigation of the quality of seeds of Anethum graveolens varieties Gribovsky and Lesnogorodsky by method of thermal analysis","authors":"E. Zueva, S. Belopukhov, Ravil F. Baybekov","doi":"10.37952/ROI-JBC-01/20-64-12-45","DOIUrl":null,"url":null,"abstract":"The paper presents data on the study of the chemical composition of dill (Anethum graveolens L) using foliar treatment of vegetative plants with the growth-regulating agent Nicosulfuron [2-(4,6-dimethoxypyrimidin-2-ylcarbomoyl-sulfamoyl) -N,N-dimethylnicotinamide]. Field experiments were carried out at the agrobiological station of the Humanitarian and Technological University of the city of Orekhovo-Zuevo, Moscow Region in 2016-2018. The soil of the experimental plots is sod-podzolic medium loamy. Plants were treated with a solution of Nicosulfuron with a concentration of 0.1 g/l according to the active substance. It was found that foliar treatment of vegetative plants with a solution of 2-(4,6-dimethoxypyrimidin-2-ylcarbomoyl-sulfamoyl)-N,N-dimethylnico-tinamide led to a change in the concentrations of macrocomponents in the seeds of dill varieties Gribovsky and Lesnogorodsky. Differential thermal analysis of DTA) of dill seeds was carried out using a thermoanalytical complex based on a derivatograph. The sample heating rate in a platinum crucible was 5, 10, and 20 degrees per minute. The DTA method showed a significant difference in the component composition of the organic matter of seeds of both varieties. 6 organic components can be grouped into two groups – with thermal decomposition temperatures of 200-400 °C and 400-600 °C. The treatment with Nicosulfuron leads to a shift in the accumulation of synthesized spare components of seeds towards easily degradable (up to 400 °C) components. This treatment effect is manifested in the fact that in the total mass of organic components of dill seeds (at the level of 87%), the fraction of readily decomposable organic matter is 64-70% for both varieties. In the control variant, without treatment with the drug, the biosynthesis of hardly degradable components, probably having a high molecular weight, and for high-molecular compounds having a high degree of polymerization, occurs. At the same time, the total activation energy for organic compounds in the control is 30-40% higher compared to the samples that were treated with Nicosulfuron.","PeriodicalId":9405,"journal":{"name":"Butlerov Communications","volume":"121 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2020-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Butlerov Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.37952/ROI-JBC-01/20-64-12-45","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The paper presents data on the study of the chemical composition of dill (Anethum graveolens L) using foliar treatment of vegetative plants with the growth-regulating agent Nicosulfuron [2-(4,6-dimethoxypyrimidin-2-ylcarbomoyl-sulfamoyl) -N,N-dimethylnicotinamide]. Field experiments were carried out at the agrobiological station of the Humanitarian and Technological University of the city of Orekhovo-Zuevo, Moscow Region in 2016-2018. The soil of the experimental plots is sod-podzolic medium loamy. Plants were treated with a solution of Nicosulfuron with a concentration of 0.1 g/l according to the active substance. It was found that foliar treatment of vegetative plants with a solution of 2-(4,6-dimethoxypyrimidin-2-ylcarbomoyl-sulfamoyl)-N,N-dimethylnico-tinamide led to a change in the concentrations of macrocomponents in the seeds of dill varieties Gribovsky and Lesnogorodsky. Differential thermal analysis of DTA) of dill seeds was carried out using a thermoanalytical complex based on a derivatograph. The sample heating rate in a platinum crucible was 5, 10, and 20 degrees per minute. The DTA method showed a significant difference in the component composition of the organic matter of seeds of both varieties. 6 organic components can be grouped into two groups – with thermal decomposition temperatures of 200-400 °C and 400-600 °C. The treatment with Nicosulfuron leads to a shift in the accumulation of synthesized spare components of seeds towards easily degradable (up to 400 °C) components. This treatment effect is manifested in the fact that in the total mass of organic components of dill seeds (at the level of 87%), the fraction of readily decomposable organic matter is 64-70% for both varieties. In the control variant, without treatment with the drug, the biosynthesis of hardly degradable components, probably having a high molecular weight, and for high-molecular compounds having a high degree of polymerization, occurs. At the same time, the total activation energy for organic compounds in the control is 30-40% higher compared to the samples that were treated with Nicosulfuron.
本文介绍了生长调节剂nico磺隆[2-(4,6-二甲氧基嘧啶-2-酰基氨基磺基)- n, n-二甲基烟酰胺]对营养植物叶面处理莳萝(Anethum graveolens L)化学成分的研究数据。2016-2018年,在莫斯科州奥列霍沃-祖埃沃市人道主义和技术大学的农业生物站进行了实地实验。试验田土壤为灰化土中壤土。用浓度为0.1 g/l的尼可隆溶液处理植株。研究发现,营养植物叶面处理2-(4,6-二甲氧基吡啶-2-酰基氨基磺酰基)- n, n-二甲基nico-tinamide溶液可改变莳蕾品种Gribovsky和Lesnogorodsky种子中主要成分的浓度。采用基于衍生物的热分析配合物对莳萝种子的DTA进行了差热分析。样品在铂坩埚中的加热速率为每分钟5度、10度和20度。DTA分析结果表明,两品种种子有机质组分组成差异显著。6种有机组分可分为热分解温度200-400℃和400-600℃两组。用尼科磺隆处理导致种子合成备用成分的积累转向易于降解(高达400°C)的成分。这种处理效果表现在两个品种莳萝种子有机成分总质量(87%)中,易分解有机质的比例为64-70%。在对照变异体中,不经药物处理,发生难以降解成分的生物合成,可能具有高分子量,以及具有高度聚合的高分子化合物。同时,对照样品中有机化合物的总活化能比经尼磺隆处理的样品高30-40%。