The effect of surface treatment of silica nanoparticles on the breakdown strength of mineral oil

Huifei Jin, P. Morshuis, J. Smit, T. Andritsch
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引用次数: 26

Abstract

In previous work, the results of AC breakdown tests showed that unmodified silica nanoparticles improve the breakdown strength of mineral oil based nanofluids, especially at a relatively high humidity level of around 25 ppm. It was proposed that, since the hydrophilic surface of unmodified silica nanoparticles can absorb water, this would lead to a reduction of free moisture in the bulk of the oil, which has a strong influence on the breakdown strength. In the present study this proposition is verified, by comparing the breakdown strength of two mineral oil based nanofluids: a reference with unmodified silica nanofluid and a nanofluid with Z-6011 modified silica. The silane coupling agent Z-6011 turns the surface of silica nanoparticles hydrophobic, thus preventing water adsorption.
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纳米二氧化硅表面处理对矿物油击穿强度的影响
在之前的工作中,交流击穿测试的结果表明,未经改性的二氧化硅纳米颗粒提高了矿物油基纳米流体的击穿强度,特别是在相对较高的湿度水平(约25 ppm)下。我们提出,由于未经改性的二氧化硅纳米颗粒的亲水表面可以吸收水分,这将导致油中大块的自由水分减少,这对击穿强度有很大的影响。在本研究中,通过比较两种矿物油基纳米流体的击穿强度来验证这一观点:一种是未经改性的二氧化硅纳米流体,另一种是经过Z-6011改性的二氧化硅纳米流体。硅烷偶联剂Z-6011使二氧化硅纳米颗粒表面疏水,从而防止水吸附。
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