A Possible Interpretation for the High Catalytic Activity of Heat-Treated Non-Precious Metal Nx/C Catalysts for O2 Reduction in Terms of Their Formal Potentials

Abstract

In this paper we compare the catalytic activitites of untouched metal macrocyclic and pyrolyzed catalysts for ORR in acid versusthe formal potential of the catalyst and find in general that the catalysts reported in the literature exhibiting more positive formalpotentials are more active for ORR. These trends observed could serve as a hint for the development more active non-precious metalcatalysts for fuel cells.©2012 The Electrochemical Society. [DOI: 10.1149/2.032206esl] All rights reserved.Manuscript submitted January 16, 2012; revised manuscript received April 13, 2012. Published April 27, 2012.