Mobility of positively charged ions in supercritical helium

H. G. Tarchouna, F. Aitken, N. Bonifaci, K. von Haeften, J. Eloranta
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Abstract

The mobility of positively charged ions in supercritical helium at temperatures from 6 to 11 K and up to 20 bar was measured using corona discharges. Regions of increased and decreased hydrodynamic radius are interpreted in terms of growth, compression and solidification of ion clusters. Modelling of the mobility using a thermodynamic state equation for the ion-helium mixed system and a temperature dependent Cunningham correction provides best match with experimental data for a van der Waals helium-ion interaction term. Regions of large hydrodynamic radius and large compressibility are attributed to liquid-like behaviour.
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超临界氦中带正电离子的迁移率
用电晕放电测量了超临界氦中6 ~ 11 K和20 bar温度下正电离子的迁移率。水动力半径增加和减少的区域是根据离子簇的生长、压缩和凝固来解释的。利用离子-氦混合系统的热力学状态方程和温度相关的坎宁安校正对迁移率进行建模,提供了与范德华氦离子相互作用项的实验数据的最佳匹配。大流体动力半径和大压缩率的区域归因于类液体行为。
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