Rapid Methods of Synthesis of Stilbene and Phenylethynylstilbene Arms

Issa Samb, V. Michelet
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Abstract

Stilbene and phenylethynylstilbene units are excellent candidates for fluorescent sensor synthesis. In this paper we show a fast and efficient method for the preparation of fluorophores based on biphenyl nuclei with phenylene-vinylene units functionalized by donor groups. Using pallado catalysed coupling reactions of Sonogashira types and Wittig or Wittig-Horner reaction, the stilbene and phenylethylsilbene arms functionalized with O-alkyl and N-alkyl donor groups were synthesized.
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二苯乙烯和苯乙基二苯乙烯臂的快速合成方法
二苯乙烯和苯基乙基二苯乙烯是合成荧光传感器的优秀候选单位。在本文中,我们展示了一种快速和有效的方法来制备基于苯基-乙烯基基团官能团的联苯核荧光团。利用钯催化的Sonogashira型偶联反应和Wittig或Wittig- horner反应,合成了o -烷基和n -烷基给基功能化的苯乙烯臂和苯基乙基硅烷臂。
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