A Study on Green Synthesis of Nano Cu Compounds (Malachite and Rouaite), Using Moringa oleifera Leaf Extract and their Photocatalytic, Antifungal, Anti-Inflammatory, and Antioxidant Properties

S. Darani, N. N. Devi, R. Rajakumari
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Abstract

Nano copper compounds (Malachite and Rouaite) were synthesized using Moringa oleifera leaf extract as the reducing agents and characterized by X-ray diffraction and Scanning electron microscopic analysis, respectively, for structure and morphology. The UV-vis absorption analysis of Malachite exhibits multiple peaks, and the energy bandgap obtained from the Taue plot was 5.32 eV for malachite and 3.7 eV for Rouaite. The photoluminescence spectra of Malachite and Rouaite show broadband emission in the green region of the visible spectrum. The photocatalytic activity of Malachite and Rouaite was examined with the natural dye of beetroot (Beta vulgaris) extract and observed that the absorption peak intensity of the dye decreases as the time of exposure to sunlight increases, indicating the degrading effect of the synthesized samples. The antifungal activity of Malachite and Rouaite with Candida albicans by agar disc diffusion method showed that Rouaite has more enhanced antifungal activity than Malachite. Thus, it is suggested that the green synthesized Rouaite and Malachite may be used in medicine for their antifungal and anti-inflammatory activities.
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辣木叶提取物绿色合成纳米铜化合物(孔雀石和柔石)及其光催化、抗真菌、抗炎和抗氧化性能的研究
以辣木叶提取物为还原剂,合成孔雀石和柔石两种铜纳米化合物,分别用x射线衍射和扫描电镜对其结构和形貌进行了表征。孔雀石的紫外可见吸收分析呈多峰分布,Taue图中孔雀石的能带隙为5.32 eV,柔石的能带隙为3.7 eV。孔雀石和柔石的光致发光光谱在可见光谱的绿色区域显示宽带发射。以甜菜根(Beta vulgaris)提取物为天然染料,考察了孔雀石和Rouaite的光催化活性,观察到染料的吸收峰强度随着日照时间的增加而降低,表明合成的样品具有降解效果。琼脂盘扩散法测定孔雀石和柔石对白色念珠菌的抑菌活性,结果表明柔石的抑菌活性比孔雀石强。因此,建议绿色合成的柔石和孔雀石具有抗真菌和抗炎的作用,可用于医学。
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