RHEOLOGY CHARACTERIZATION OF WATER-IN-OIL EMULSIONS

P. Silva, M. Naccache, Paulo Mendes
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Abstract

One of the main problems of the oil industry is hydrate formation. Hydrates of natural gas are crystalline solids, formed by the association of water molecules and molecules of certain gas in an organized structure. Its occurrence is a natural concern for the Oil & Gas Industry, given the potential risk of flow assurance. Nevertheless, ever-challenging scenarios encourage the search for risk assessment methodologies seeking to identify conditions where hydrates will form, but with little possibility of plugging. The present study aims to develop a water-in-oil emulsion capable of giving hydrate at ambient pressure. This work analyzes the effects of water and surfactant concentration in viscosity, storage, and dissipation modulus in a model water-in-oil emulsion. Rheological data are obtained for several combinations of emulsion components, and their mechanical behavior is related to hydrate formation.
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油包水乳剂的流变学表征
石油工业的主要问题之一是水合物的形成。天然气水合物是结晶固体,由水分子和某些气体分子在一个有组织的结构中结合而成。考虑到流动保障的潜在风险,它的发生是油气行业的一个自然问题。然而,不断具有挑战性的场景鼓励人们寻找风险评估方法,以确定水合物形成的条件,但几乎没有堵塞的可能性。本研究旨在研制一种能在常压下生成水合物的油包水乳液。本文分析了水和表面活性剂浓度对油包水乳液粘度、储存量和耗散模量的影响。得到了几种乳液组分组合的流变数据,它们的力学行为与水合物的形成有关。
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