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SYNTHETIC WATER-IN-OIL EMULSIONS: EFFECT OF OIL COMPOSITION ON STABILITY AND DEMULSIFIER PERFORMANCE 合成油包水型乳液:油成分对稳定性和破乳剂性能的影响
Pub Date : 2024-07-02 DOI: 10.5419/bjpg2024-0007
M. R. Ferreira, G. S. M. Reis, R. C. P. Nunes, E. F. Lucas
Stable water-in-oil (w/o) emulsions are undesirable from an operational standpoint, with the asphaltenes present in petroleum being considered the main stabilizers of these emulsions. Demulsifiers are agents added to destabilize these emulsions. The objective of this work is to evaluate the stability of w/o emulsions formed from an oil phase with different polarities (kerosene and toluene) containing asphaltene fractions C3I, C5I, and C7I, and how these systems affect the action of a demulsifier additive. Systems containing asphaltenes in toluene were more stable when using the C7I fraction due to its greater polarity and, consequently, considerable action at the interface. With the oil phase composed of a less polar solvent (kerosene), the C3I fraction increased the stability of the emulsion by reducing the action of the demulsifying additive, with an upper asphaltenes concentration limit of 1.0% observed where the action of the demulsifying agent was affected.
从操作角度来看,稳定的油包水乳状液是不可取的,石油中的沥青质被认为是这些乳状液的主要稳定剂。破乳化剂是用来破坏乳状液稳定性的添加剂。这项工作的目的是评估由含有沥青质馏分 C3I、C5I 和 C7I 的不同极性油相(煤油和甲苯)形成的不含油乳状液的稳定性,以及这些体系如何影响破乳化剂添加剂的作用。在使用 C7I 馏分时,甲苯中含有沥青质的体系更加稳定,这是因为 C7I 馏分的极性更大,因此在界面上的作用也更大。当油相由极性较弱的溶剂(煤油)组成时,C3I馏分可通过减少破乳剂添加剂的作用来提高乳液的稳定性,在沥青质浓度上限为1.0%时,破乳剂的作用会受到影响。
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引用次数: 0
WELL-TO-WELL (W2W) ELECTROMAGNETIC TOMOGRAPHY MODELING ADVANCEMENT: IMPROVING PRECISION AND EFFECTIVENESS WITH REGULARIZATION 井到井(W2W)电磁层析成像建模进展:利用正则化提高精度和有效性
Pub Date : 2024-07-02 DOI: 10.5419/bjpg2024-0005
J. M. Santana, V. C. T. de Souza, H. O. da Rocha, J. A. O. Marinho
This research describes the direct and inverse problems of cross-well electromagnetic tomography. The model geometry has azimuthal symmetry, which simplifies the forward modeling and the inversion procedure. In the direct problem, the finite element method is used in the numerical solution of the Helmholtz equation. In the inverse problem, the study discusses the use of three stabilizer functionals: Global Smoothness (GS), Total Variation (TV), and Absolute Equality (AE). The first uses a smoothing function in the L2 norm, while the latter uses smoothing in the L1 norm, for it accepts abrupt changes between adjacent parameters. The results show that the TV method generated good estimates of both geometry and conductivity of the bodies, both for small and large conductivity contrast between the targets and the surrounding environment. Through the results, one can also observe that the regularization of the Total Variation presented a better estimate of the parameters than the Global Smoothness. In most of the synthetic models used in this work, the best estimates of the proposed model occurred when Absolute Equality constraints were used on the cells at the edges of the inversion grid, in addition to the stabilizer functional.
本研究描述了跨井电磁层析成像的正演和反演问题。模型几何具有方位对称性,从而简化了正演建模和反演过程。在直接问题中,有限元法用于亥姆霍兹方程的数值求解。在反演问题中,研究讨论了三个稳定器函数的使用:全局平滑 (GS)、总变异 (TV) 和绝对相等 (AE)。前者使用 L2 规范的平滑函数,后者使用 L1 规范的平滑函数,因为它接受相邻参数之间的突然变化。结果表明,无论目标与周围环境的电导率对比大小如何,TV 方法都能很好地估计物体的几何形状和电导率。通过这些结果,我们还可以发现,总变异正则化比全局平滑度对参数的估计更好。在这项工作中使用的大多数合成模型中,除了稳定器函数外,在反演网格边缘的单元上使用绝对等值约束时,所提出模型的估计结果最好。
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引用次数: 0
IMMISCIBLE VISCOUS FINGERING MODELING OF TERTIARY POLYMER FLOODING BASED ON REAL CASE OF HEAVY OIL RESERVOIR MODEL 基于重油油藏模型实际案例的三次聚合物水淹不相溶粘指模
Pub Date : 2024-07-02 DOI: 10.5419/bjpg2024-0006
B. M. O. Silveira, V. Botechia, D. J. Schiozer, A. Skauge
In immiscible displacements, lower viscosity injected fluids with higher mobility than crude oil can create viscous fingers, affecting displacement efficiency. The Buckley–Leverett approach for relative permeabilities (kr) may not represent accurately 2D features like increased water saturation in viscous fingering. Based on the physics issue, this work applies Sorbie's 4-Steps methodology to a 3D simulation of an offshore heavy oil reservoir focusing on waterflooding and tertiary polymer flooding, assessing their impact on oil production forecasts. It also explores the application of this methodology to coarse grid simulation models, employing pseudo kr functions by data assimilation. During tertiary polymer injection, two processes were identified in oil displacement: viscous crossflow mechanism and oil bank mobilization by a second finger. This combination resulted in earlier and increased oil production. For both strategies, refining the grid increased simulation runtime from minutes to days compared to coarse grids, making it impractical for intensive processes. From data assimilation, the best solution with matched field indicators reduced runtime from days to minutes. This study expanded the 4-Steps methodology for 3D reservoir simulation, proposing kr as uncertainties. Data assimilation enhances the methodology, generating pseudo kr for coarser grid simulations, reducing computational costs, and capturing small-scale phenomena.
在不相溶位移中,比原油流动性更高的低粘度注入流体会产生粘指,影响位移效率。相对渗透率(kr)的 Buckley-Leverett 方法可能无法准确反映二维特征,如在粘指过程中水饱和度的增加。基于物理学问题,这项工作将索比四步方法应用于海上重油储层的三维模拟,重点是注水和三次聚合物注水,评估它们对石油产量预测的影响。研究还探讨了如何将该方法应用于粗网格模拟模型,并通过数据同化采用伪 kr 函数。在三次聚合物注入过程中,确定了石油位移的两个过程:粘性横流机制和第二根手指调动油库。这两个过程的结合使石油产量提前并增加。对于这两种策略,与粗网格相比,细化网格会将模拟运行时间从几分钟增加到几天,因此对于密集流程来说并不实用。通过数据同化,最佳解决方案与匹配的实地指标将运行时间从几天缩短到几分钟。这项研究扩展了三维储层模拟的 4 步方法,提出了 kr 作为不确定因素。数据同化增强了该方法,为更粗的网格模拟生成了伪 kr,降低了计算成本,并捕捉到了小尺度现象。
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引用次数: 0
SCALE INHIBITOR SQUEEZE TREATMENT: AN ADVANCED BIBLIOMETRIC ANALYSIS 阻垢剂挤压处理:高级文献计量分析
Pub Date : 2024-07-02 DOI: 10.5419/bjpg2024-0008
R. T. Landim, M. M. F. Melo Neta, F. J. S. Barros, C. L. Cavalcante Jr., F. M. T. Luna
The scale inhibitor squeeze treatment is an important method used in the petroleum industry to control formation of inorganic deposition within the oil production wells. This treatment increases the life cycle of petroleum production by preventing or reducing the formation and growth of salt crystals. In recent years, studies on inhibitor squeeze treatments have been expanding and diversifying with the goal of improving the lifespan and reducing treatment costs. This study reports an advanced bibliometric analysis from 1970 to 2023, illustrating the extent of research on inhibitor squeeze treatments to prevent the formation of inorganic scale, with a systematic survey since the first registered publication. It highlights the evolution of research reports, assessing the relationships between institutions, journals, and authors, identifying of potential needs to be addressed by future investigations.
阻垢剂挤压处理是石油工业用于控制采油井内无机沉积物形成的一种重要方法。这种处理方法可以防止或减少盐晶体的形成和生长,从而延长石油生产的生命周期。近年来,有关抑制剂挤压处理的研究不断扩大和多样化,目的是提高使用寿命和降低处理成本。本研究报告对 1970 年至 2023 年的文献计量学进行了高级分析,说明了抑制剂挤压处理在防止无机垢形成方面的研究程度,并对首次登记发表的文献进行了系统调查。它强调了研究报告的演变,评估了机构、期刊和作者之间的关系,确定了未来调查需要解决的潜在需求。
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引用次数: 0
IMPROVING MICROBIAL CONTROL IN PRODUCED WATER FROM OIL FIELDS: A 5-STEP APPROACH 改善油田采出水的微生物控制:5 步法
Pub Date : 2023-12-21 DOI: 10.5419/bjpg2023-0015
G. F. Pereira, T. R. Rosin, B. Braga, G. Corção
Microbial control in oil fields can be considered a complex subject, since microbiome diversity and physical-chemical characteristics of produced water (PW) originate a unique profile in oil fields. Standard biocides are used as chemical treatment, but the toxicity and the high volumes can cause elevated environmental impacts. Treatment effectiveness and, consequently, reduction of environmental impact may be improved through an adequate planning. The present study examines the bacterial resistance mechanisms to biocides and suggests a 5-step approach for the treatment planning: 1) determination of objectives; 2) bioaudit; 3) selection of biocide(s) in laboratory; 4) selection of representative Key Performance Indicators (KPI); and 5) monitoring of the treatment. Finally, this article demonstrates an optimization of a biocide treatment using the 5-step approach. The results show a reduction of approximately 50% in the dosage of the biocide, as well as reduction in frequency of dosage.
油田中的微生物控制可以说是一个复杂的课题,因为微生物群的多样性和采出水(PW)的物理化学特性造就了油田独特的概况。标准杀菌剂被用作化学处理剂,但其毒性和高用量会对环境造成严重影响。通过适当的规划可以提高处理效果,从而减少对环境的影响。本研究探讨了细菌对杀菌剂的抗药性机制,并提出了处理规划的五步方法:1)确定目标;2)生物审计;3)在实验室选择杀菌剂;4)选择有代表性的关键绩效指标(KPI);5)监测处理情况。最后,本文展示了使用五步方法对杀菌剂处理的优化。结果表明,杀菌剂的用量减少了约 50%,用药频率也有所降低。
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引用次数: 0
ANALYSIS OF SAND PRODUCTION CONTROL IN A MATURE OIL RESERVOIR THROUGH ELECTRICAL WELL PROFILES 通过电井剖面分析成熟油藏的采砂控制
Pub Date : 2023-12-21 DOI: 10.5419/bjpg2023-0009
I. S. Melo, V. L. A. Gomes, M. A. Costa Júnior, E. V. Bautista
The sand production happens when the reservoir begins its productive life, and the consolidation of the grains that compose the framework of the oil-producing formation is not enough to keep them cohesive. The front of the drag force is caused by the flow of fluids inside the pores of the rock-reservoir. Therefore, reservoir parameters must be analyzed to observe how they behave considering the production of solids. The operational parameters used in this study were compressional wave, shear wave and gamma ray profiles, depth, average overburden density, reservoir fluid pressure, and bottom pressure in flow during production. These data allowed us to predict the production of sand in a mature oil reservoir. The results show that in the zones that presented solids production, through the control of the dynamic pressure, it is possible to control the production of sand and determine the critical point of its production.
当储油层开始生产时,就会出现产砂现象,而构成产油层框架的颗粒的固结不足以保持其内聚力。阻力的前端是岩石-储层孔隙中的流体流动造成的。因此,必须对储层参数进行分析,以观察它们在生产固体物质时的表现。本研究中使用的运行参数包括压缩波、剪切波和伽马射线剖面、深度、平均覆盖层密度、储层流体压力以及生产过程中的流动底压。通过这些数据,我们可以预测成熟油藏的产砂量。结果表明,在出现固体生产的区域,通过控制动压,可以控制砂的生产,并确定其生产的临界点。
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引用次数: 0
APPLICATION OF WATER FLOODING AND WATER ALTERNATIVE GAS (WAG) FLOODING TECHNIQUES IN A CARBONATE RESERVOIR: INTEGRATION OF RESERVOIR AND PRODUCTION SYSTEMS FOR DECISION MAKING 在碳酸盐岩储层中应用水淹和水替代气体(wag)淹没技术:整合储层和生产系统以进行决策
Pub Date : 2023-12-21 DOI: 10.5419/bjpg2023-0012
J. C. von Hohendorff Filho, I. R. S. Victorino, A. Bigdeli, D. J. Schiozer
The objective of this work is to evaluate the impact of integration between reservoir and production systems on the decision making for field production development. The authors demonstrated, in a benchmark case, the applicability of water injection (WI) and water alternating gas injection (WAG) techniques for various production systems by proposing a novel methodology. This work explores three optimization approaches: (1) based on the complete model considering integrated systems, (2) for production system based solely on reservoir model and followed by the integration and optimization of production system, and (3) derived from (2) considering subsequent integration and optimization for complete model. In the implementation step, production strategies are applied in a reference model. This work compares production strategies, reservoir performance forecast, and the net present value (NPV) objective function. The integrated models yeild similar objective-function values by utilizing a production system that does not alter the bottom-hole conditions significantly, thereby replicating the behavior observed in the non-integrated model. The results of non-integrated reservoir optimizations should be used with caution for decision-making purposes, as the subsequent integration may cause the changes to the the production forecasts. The differences in reservoir behaviors can be attributed to the changes in the dynamics (movement) of fluids from the reservoir to the wells and the type of recovery mechanism affected by well positioning. The implementation of production strategies in the reference model resulted in lower values of NPV (20% for WI and 60% for WAG) than those obtained in the optimization step. The findings demand caution in the application of closed-loop procedures to prevent biased or inaccurate assessments of decisions made solely based on reservoir models. The application of this work can be considered an import study for Carbon Capture Utilization and Storage (CCUS), as well as for energy transition based on WAG optimization.
这项工作的目的是评估储层与生产系统集成对油田生产开发决策的影响。作者通过提出一种新方法,在一个基准案例中展示了注水(WI)和水气交替注入(WAG)技术在各种生产系统中的适用性。这项工作探索了三种优化方法:(1) 基于考虑集成系统的完整模型;(2) 仅基于储层模型的生产系统,然后对生产系统进行集成和优化;(3) 从 (2) 派生,考虑完整模型的后续集成和优化。在实施步骤中,生产策略应用于参考模型。这项工作对生产策略、储层性能预测和净现值(NPV)目标函数进行了比较。集成模型通过使用一个不会显著改变井底条件的生产系统,从而复制了非集成模型中观察到的行为,得出了相似的目标函数值。非集成油藏优化的结果应谨慎用于决策目的,因为随后的集成可能会导致生产预测发生变化。储层行为的差异可归因于流体从储层到油井的动态(运动)变化以及受油井定位影响的采收机制类型。参考模型中生产策略的实施导致净现值(WI 为 20%,WAG 为 60%)低于优化步骤中获得的净现值。这些发现要求在应用闭环程序时要谨慎,以防止仅根据储层模型做出的决策评估有偏差或不准确。这项工作的应用可视为碳捕集利用与封存(CCUS)以及基于 WAG 优化的能源转型的一项重要研究。
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引用次数: 0
MODEL-BASED OPTIMIZATION OF ICVs’ CONTROL FOR PRODUCERS, INJECTORS, AND WAG-CO2 CYCLES SIZE IN A CARBONATE RESERVOIR UNDER UNCERTAINTY 以模型为基础优化碳酸氢盐储层中对生成器、喷射器和 WAG-CO2 循环大小的 ICV 控制
Pub Date : 2023-12-21 DOI: 10.5419/bjpg2023-0010
V. Botechia, D. J. Schiozer
Life cycle management of oil fields involves complex decisions, with many variables to be considered. In some fields of the Brazilian pre-salt, this task is even more challenging given the ultra-deep water location, with an expressive amount of gas (including CO2) production. This feature becomes a restricting factor for oil production in these types of fields, and a proper management is essential to overcome this issue, improving both production and economic returns. Therefore, Water-Alternate-Gas (WAG) is often used as an Enhanced Oil Recovery- EOR mechanism, providing a better mobility control, improving reservoir sweep and oil recovery. Moreover, WAG can be an alternative for recycling the produced gas, providing an adequate destination (mainly for CO2) and avoiding environmental problems. In this case, we name the method as WAG-CO2. Moreover, Interval Control Valves (ICVs) are also a good alternative to deal with these fields, since they work as flow control devices and allow for a better balance of the fluid flow in the reservoir. In this work, we evaluate the impact of the use of ICVs in producers, injectors, along with WAG cycles size to improve the performance of a developed field. The work consists of two parts. In Part I, using a single simulation model, we performed (1) six hierarchical optimization approaches to verify if the order in which the optimization occurs influences the final results, and (2) a joint optimization of all parameters for comparison purposes. The final strategies are simulated in a reference case (representing the “true response” of the field) to evaluate how the achieved control rules would behave in a real field. In Part II, we considered a probabilistic procedure, applying one of the hierarchical approaches in several representative models (RMs) expressing uncertain scenarios. In this case, we compared nominal optimization of individual RMs against a robust optimization (in which all RMs are optimized simultaneously). The study is applied to the benchmark case SEC1_2022, a synthetic model analogous to a pre-salt field. The results show an expressive increase in the economic return of the field with a proper operation of the ICVs and size of the WAG-CO2 cycles, despite the platform being restricted by gas production capacity. This result occurred because of a better balance in fluid flow through the reservoir and among wells. Moreover, in the first part of the work, all hierarchical approaches presented very similar results in terms of NPV, so the order of the optimization steps did not significantly affect the results. The non-hierarchical approach presented a slightly better result, but still close to those obtained in the hierarchical approaches. Furthermore, the most impacting variable was the ICV for producers, followed by ICV for injectors and, then, WAG-CO2 cycles. Similar tendencies were observed in the second part of the work, with higher expected economic return for the robust optimization.
油田的生命周期管理涉及复杂的决策,需要考虑许多变量。在巴西前盐层的一些油田,由于地处超深水区,天然气(包括二氧化碳)产量巨大,因此这项任务更具挑战性。这一特点成为这类油田石油生产的一个限制因素,而适当的管理对于克服这一问题、提高产量和经济收益至关重要。因此,水-替代气(WAG)经常被用作一种提高石油采收率的机制,可以提供更好的流动性控制,提高储层扫描和石油采收率。此外,WAG 还可以作为回收利用产出气体的替代方法,提供适当的去向(主要是 CO2),避免环境问题。在这种情况下,我们将这种方法命名为 WAG-CO2。此外,间歇控制阀(ICV)也是处理这些气田的一个很好的替代方法,因为它们可以作为流量控制装置,更好地平衡储层中的流体流动。在这项工作中,我们评估了在生产商、注入商中使用间歇控制阀(ICV)的影响,以及 WAG 循环尺寸对改善已开发油田性能的影响。这项工作由两部分组成。在第一部分中,我们使用单一模拟模型,执行了(1)六种分层优化方法,以验证优化顺序是否会影响最终结果,以及(2)所有参数的联合优化,以进行比较。我们在一个参考案例(代表实地的 "真实反应")中模拟了最终策略,以评估所实现的控制规则在真实实地中的表现。在第二部分中,我们考虑了一种概率程序,将其中一种分层方法应用于表达不确定情况的几个代表性模型(RM)中。在这种情况下,我们将单个 RM 的名义优化与稳健优化(同时优化所有 RM)进行了比较。研究应用于 SEC1_2022 基准案例,这是一个类似于前盐田的合成模型。结果表明,尽管平台受到天然气生产能力的限制,但通过适当运行 ICV 和 WAG-CO2 循环的大小,油气田的经济回报率有了明显提高。出现这一结果的原因是,流经储层和各井的流体流量更加平衡。此外,在工作的第一部分,所有分层方法的净现值结果都非常相似,因此优化步骤的顺序对结果没有显著影响。非分层方法的结果稍好,但仍与分层方法的结果接近。此外,影响最大的变量是生产商的 ICV,其次是喷射器的 ICV,然后是 WAG-CO2 循环。在工作的第二部分也观察到类似的趋势,稳健优化的预期经济回报更高。
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引用次数: 0
LIQUEFACTION OF COFFEE BIOMASS WITH RESIDUAL GLYCERIN: A STUDY OF RENEWABLE FUEL PRODUCTION 咖啡生物质与残留甘油的液化:可再生燃料生产研究
Pub Date : 2023-12-21 DOI: 10.5419/bjpg2023-0011
E. R. Silva, E. L. Barros Neto, P. F. P. Nascimento, H. M. N. Oliveira, G. G. Medeiros, L. J. N. Duarte
The present study analyzes the hydrothermal liquefaction of residual coffee biomass using glycerin from the production of biodiesel through the homogeneous route. The reactions occurred by varying the glycerol/water ratio (1:0, 1:1, and 1:2) and the solvent/biomass ratio (70 and 90%) with heating at 180°C for 30 minutes (mixing phase) and at 250°C for 15 minutes. The products obtained were identified as light bio-oil (BOL), heavy bio-oil (BOP), gaseous fraction (FG), and solids (SOL). These products were submitted to characterization through density, thermogravimetry, and viscosity analyses. The condition that generated the highest oil yields was the one where 70% solvent and a glycerin/water ratio of 1:2 were used, producing approximately 83% of bio-oils. In this perspective, coffee biomass and residual glycerin were suitable for use in the hydrothermal liquefaction process.
本研究分析了利用甘油通过均相途径生产生物柴油的残余咖啡生物质的水热液化。通过改变甘油/水的比例(1:0、1:1 和 1:2)和溶剂/生物质的比例(70% 和 90%),在 180°C 下加热 30 分钟(混合阶段)和 250°C 下加热 15 分钟进行反应。得到的产物被鉴定为轻质生物油 (BOL)、重质生物油 (BOP)、气态馏分 (FG) 和固体 (SOL)。这些产物通过密度、热重和粘度分析进行鉴定。产油量最高的条件是使用 70% 的溶剂和甘油/水比例为 1:2,产生约 83% 的生物油。从这个角度来看,咖啡生物质和残留甘油适合用于水热液化工艺。
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引用次数: 0
REACTIVE FLOW IN CARBONATE ROCKS FROM LACUSTRINE ENVIRONMENTS: THE EFFECTS OF PRESSURE AND FLUID SALINITY 湖沼环境碳酸盐岩中的反应流:压力和流体盐度的影响
Pub Date : 2023-12-21 DOI: 10.5419/bjpg2023-0013
K. C. Silva, L. F. Cury, L. F. L. Luz Junior
The high production of CO2 from Brazilian pre-salt reservoirs requires research on CO2 interactions with carbonate reservoirs for enhanced oil recovery (EOR) or CO2 trapping. This interaction causes reactive phenomena that are not fully understood. Experimental tests on carbonate facies are crucial for understanding reactions and their impact on reservoir characteristics. This study investigates experimentally reactions generated by reactive fluid flow in carbonate rocks from two geological scenarios by analyzing chemical and morphological parameters before and after the tests. Salinity was the most significant parameter for reactive flow, impacting porosity for modern continental carbonate samples from Patagonia. However, the sample from the Brazilian pre-salt showed higher mineral stability and less mineral dissolution. Results provide data for simulating reactive transport in these rocks for CCS and understanding diagenetic processes' impact on reservoir quality.
巴西前盐储层的二氧化碳产量很高,需要研究二氧化碳与碳酸盐储层的相互作用,以提高石油采收率(EOR)或捕获二氧化碳。这种相互作用引起的反应现象尚未完全明了。碳酸盐岩面的实验测试对于了解反应及其对储层特征的影响至关重要。本研究通过分析试验前后的化学和形态参数,对两种地质情况下碳酸盐岩中反应性流体流动产生的反应进行了实验研究。盐度是反应流最重要的参数,对巴塔哥尼亚现代大陆碳酸盐岩样本的孔隙度产生影响。然而,来自巴西前盐层的样本显示出较高的矿物稳定性和较少的矿物溶解。研究结果为模拟这些岩石中的反应流提供了数据,以用于 CCS 并了解成岩过程对储层质量的影响。
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引用次数: 0
期刊
Brazilian Journal of Petroleum and Gas
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