The study of nanosilica in cement base materials

E. Shahbazov, A. Guvalov
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Abstract

The effect of nanoparticles of nanosilica on the characteristics of the systems of cement-sand-water is studied. In the studies, 50–110 nm nanoparticles obtained through the separation of nanosilica from the soluble glass using the method of sol-gel were applied. The characteristics of solid samples were measured after their hardening during 3-28 days. The effect of nanoadditive on the density, speed of accumulation of final durability of cement samples in squeezing was defined. Obtained results on the increase of durability in squeezing of solid cement samples should be explained with the effect of nanostructuring achieved with adding nanoparticles of silica. These particles are characterized with high specific surface and its high physical-chemical activity. It is shown that due to the effect of surface of silica nanoparticles, hydration speed of cement rises and direct formation of ordered permolecular structures of hydrates of calcium silicate structuring the cement matrix and improving its hardness occurs. The results may be applied in construction technologies for the structuring of cement materials and improving their characteristics as well: durability, density, water permeability, cold resistance.
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纳米二氧化硅在水泥基材料中的应用研究
研究了纳米二氧化硅纳米颗粒对水泥-砂-水体系性能的影响。在本研究中,采用溶胶-凝胶法将纳米二氧化硅从可溶性玻璃中分离得到50-110 nm的纳米颗粒。固体试样在3 ~ 28天硬化后测定其特性。定义了纳米添加剂对水泥试样在挤压过程中密度、累积速度和最终耐久性的影响。所获得的关于固体水泥试样在挤压过程中耐久性提高的结果,应该用添加二氧化硅纳米颗粒所实现的纳米结构效应来解释。这些颗粒具有高比表面和高物理化学活性的特点。结果表明,受纳米二氧化硅表面的影响,水泥的水化速度加快,水化硅酸钙直接形成有序的过分子结构,使水泥基体结构有序,硬度提高。研究结果可应用于水泥材料结构的施工技术,改善其耐久性、密度、透水性、耐寒性等性能。
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