{"title":"Formation products from the n-undecane oxidation reaction","authors":"U. A. Karimova","doi":"10.37474/0365-8554/2023-5-49-55","DOIUrl":null,"url":null,"abstract":"This paper presents a study of the reaction products of the liquid-phase aerobic oxidation of n-undecane by various spectral methods. Chromium mass spectral analysis indicates the formation of valeric, hexanoic, heptanoic, octanoic and nonenoic acids, including caprylic anhydride. The NMR spectrum reveals signals from the conversion of the paraffinic hydrocarbon into olefinic and naphthenic groups. It has been determined that in the oxidative system of gamma radicals, great opportunities are created for the formation of oxidation products of various isostructures.","PeriodicalId":8668,"journal":{"name":"Azerbaijan Oil Industry","volume":"1 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Azerbaijan Oil Industry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.37474/0365-8554/2023-5-49-55","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
This paper presents a study of the reaction products of the liquid-phase aerobic oxidation of n-undecane by various spectral methods. Chromium mass spectral analysis indicates the formation of valeric, hexanoic, heptanoic, octanoic and nonenoic acids, including caprylic anhydride. The NMR spectrum reveals signals from the conversion of the paraffinic hydrocarbon into olefinic and naphthenic groups. It has been determined that in the oxidative system of gamma radicals, great opportunities are created for the formation of oxidation products of various isostructures.
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