Thermodynamic Data for the Interaction of CuCl2 with Safranin (Saf) in KBr Solution at 19.1⁰C Using Glassy Carbon Electrode (CGE)

M. Diab, Adel ElSounbati, E. Gomaa, Gannat Abd Elraoof
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Abstract

The reduction and oxidation mechanisms for copper chloride were studied in 0.1M KBr in absence and presence of safranin (Saf) at 19.1°C.The mechanism of oxidation and reduction was examined. The effect of scan rate for the redox reaction of CuCl2 in absence and presence of safranin (Saf) was carried oue to explain the type of reactions for this electrochemical process. Thermodynamic parameters such as stability constants and Gibbs free energies for the complex formation of the interaction of CuCl2 with safranin (Saf) were evaluated and discussed.
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使用玻碳电极(CGE)在19.1℃的KBr溶液中CuCl2与Safranin (Saf)相互作用的热力学数据
研究了在19.1℃下,在0.1M KBr中红花素(Saf)和红花素(Saf)不存在的情况下,氯化铜的还原氧化机理。探讨了氧化还原机理。研究了扫描速率对CuCl2在不存在和不存在红花素(Saf)情况下氧化还原反应的影响,以解释该电化学过程的反应类型。讨论了CuCl2与safranin (Saf)相互作用形成络合物的热力学参数,如稳定常数和吉布斯自由能。
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