All-Carbon [60]Fullerene Oligomers of Pearl-Necklace Type

N. Dragoe, K. Nakahara, H. Shimotani, L. Xiao, S. Tanibayashi, T. Higuchi, K. Kitazawa
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引用次数: 4

Abstract

Abstract The formation of all-carbon [60]fullerene derivatives was observed in the course of the thermolysis of methano-fullerene derivatives. IR, UV-Vis, GPC, 13C-NMR, TG-MS, TOF-MS and STM data are consistent with the formation of all-carbon [60]fullerene oligomers without a direct connection between fullerene cages but through one or two carbon atoms as bridges. Molecular masses up to 8000 amu have been detected by mass spectroscopy.
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珍珠项链型全碳[60]富勒烯低聚物
摘要在甲烷-富勒烯衍生物的热裂解过程中,观察到全碳[60]富勒烯衍生物的形成。IR、UV-Vis、GPC、13C-NMR、TG-MS、TOF-MS和STM等数据均与全碳[60]富勒烯低聚物的形成一致,富勒烯笼之间没有直接连接,而是通过一个或两个碳原子作为桥接。用质谱法检测到的分子质量可达8000amu。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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TETHER-LINKED [60]FULLERENE-DONOR DYADS EVIDENCES ABOUT CARBYNE FORMATION TOGETHER WITH OTHER CARBONACEOUS MATERIAL BY THERMAL DECOMPOSITION OF DIIODOACETYLENE PHASE DIAGRAM OF K-C60 SYSTEM SOLUBILITY CORRELATION OF [60]FULLERENE IN DIFFERENT SOLVENTS AN FT-ICR STUDY ON LASER ABLATION OF GRAPHITE AND CARBON BLACK TARGETS: COSMOCHEMICAL IMPLICATIONS
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