Alkaline stripping for ultra clean bitumen from tar sand

R. Akande, A. Adeleke, P. Atanda
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Abstract

This study reports the recovery of bitumen concentrate from Ondo tar sand by alkaline leaching stripping of the associated sand. Bitumen was extracted from the tar sand as received in un-stirred and stirred state in the oven and on the magnetic stirrer hotplate, respectively, at varying 32 factorial design combinations of temperature and sodium hydroxide molar concentrations at 40 g/dm3 pulp density. The tar sand was further subjected to bitumen dissolution test and recovery of bitumen at varying pulp density. The results obtained showed that bitumen was optimally stripped from the tar sand with initial bitumen content of about 34% in the stirred condition to produce a concentrate with grade and recovery percents of 98.82 and 99.41% of bitumen, respectively. The optimal leaching stripping was obtained at 2 M sodium hydroxide concentration, at 90 °C temperature and 25 minutes contact time. The ultra-clean bitumen obtained can serve as raw material input for petroleum products recovery and as a coking additive in blend formulation of coals for metallurgical coke making.
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从沥青砂中提取超净沥青的碱性提法
本文报道了用碱性浸出法对伴生砂进行浸出,回收翁都焦油砂中的沥青精矿。在温度和氢氧化钠摩尔浓度为40 g/dm3的矿浆密度的32因子设计组合下,分别从未搅拌和搅拌状态下的沥青砂中提取沥青。对沥青砂进行了不同矿浆密度下的沥青溶解试验和沥青回收试验。结果表明,在搅拌条件下,从初始沥青含量为34%左右的沥青砂中剥离沥青,可获得沥青品位为98.82%、回收率为99.41%的精矿。在氢氧化钠浓度为2 M、温度为90℃、接触时间为25 min的条件下,浸出效果最佳。所得的超净沥青可作为石油产品回收的原料输入,也可作为炼焦用混配煤的焦化添加剂。
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