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Overview of technologies for Zn extraction from hyperaccumulating plants: Current state of research and future directions 超富集植物中锌提取技术综述:研究现状及未来发展方向
Pub Date : 2022-01-01 DOI: 10.5937/jmma2201029j
G. Jovanović, D. Ranđelović, B. Marković, M. Sokić
Phytomining, although predominantly in its early stages on the broader scientific scope of investigation, has garnered interest in metals such as Ni, Au, or rare earth elements (REE). However, Zn pollution from mine wastes, smelters, coal ash and other anthropogenic sources has become an environmental problem. Phytoremediation by hyperaccumulating plants is one of the proposed solutions to mitigate the pollution. Therefore, a need to utilize or dispose Zn hyperaccumulating plants occurred. Since studies of certain hyperaccumulating plant species have been previously conducted in order to extract metal products, similar hydrometallurgical and pyrometallurgical techniques were tried with Zn. The hydrometallurgical route was more focused on producing crude eco catalysts for organic chemistry or separating metal hydroxides by cementation. This was achieved with acid leaching of the ash which was obtained by calcinating the aboveground plant biomass. On the other hand, the pyrometallurgical route was more focused on safe and eco-friendly disposal of combustion products such as ash or biochar, while achieving zero toxic gaseous emissions from biomass pyrolysis. Regardless of the approach further research is needed to investigate the stabilization of metals that remain in the solid fraction during combustion and lowering the metal content in produced gases. So far, none of these technologies have been brought to a semi industrial scale and there is the potential of linking those two approaches together.
植物采矿虽然在更广泛的科学研究范围内主要处于早期阶段,但已经引起了人们对Ni, Au或稀土元素(REE)等金属的兴趣。然而,来自矿山废弃物、冶炼厂、煤灰等人为来源的锌污染已成为一个环境问题。利用超积累植物进行植物修复是目前提出的缓解污染的解决方案之一。因此,有必要利用或处理超富集锌植物。由于以前已经对某些超富集植物物种进行了研究,以提取金属产品,因此对锌也尝试了类似的湿法冶金和火法冶金技术。湿法冶金路线更侧重于生产有机化学用的粗生态催化剂或通过胶结分离金属氢氧化物。这是通过煅烧地上植物生物量获得的灰的酸浸来实现的。另一方面,火法冶金路线更侧重于安全环保地处理燃烧产物,如灰烬或生物炭,同时实现生物质热解的零有毒气体排放。无论采用哪种方法,都需要进一步的研究来研究燃烧过程中留在固体部分的金属的稳定性以及降低产生气体中的金属含量。到目前为止,这些技术都没有达到半工业规模,有可能将这两种方法结合起来。
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引用次数: 1
Production of niobium: Overview of processes from the mine to products 铌的生产:从矿山到产品的工艺概述
Pub Date : 2022-01-01 DOI: 10.5937/jmma2201001h
Nascimento Do, Marques Cury, C. de, Malpass Pointer, R. Alves
A number of industrial and technology sectors have been paying attention to a particular chemical element in recent years, namely niobium (Nb). There are many niobium deposits scattered around the world, and for each deposit different technologies are applied for extraction and processing due to the singular characteristics present at each site. In this paper, a review of the many technologies for niobium production will be presented starting at the mine, through techniques of niobium ore beneficiation and refining, technologies to produce ferroniobium alloy, oxides, special oxides, ammonium niobium oxalate, the separation of niobium from tantalum, and techniques to reduce and purify metallic niobium.
近年来,许多工业和技术部门一直在关注一种特殊的化学元素,即铌(Nb)。世界各地分布着许多铌矿床,由于每个地点的独特特征,每个矿床都采用不同的开采和加工技术。本文从矿山入手,通过铌矿选矿精炼技术、铌铁合金生产技术、氧化物技术、特种氧化物技术、草酸铌铵技术、铌钽分离技术、金属铌还原纯化技术等,对铌生产技术进行了综述。
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引用次数: 0
Selection of collector composition and temperature conditions for diamond foam separation 金刚石泡沫分离的捕收剂组成及温度条件的选择
Pub Date : 2022-01-01 DOI: 10.5937/jmma2201021m
V. Morozov, E. Kovalenko, G. Dvoichenkova, I. Pestryak, S. Lezova
Quantitative and qualitative regularities of a collector low and high molecular weight fractions distribution between solid and liquid phases in foam separation process were determined with the use of extraction-spectrophotometrical technique. The feasibility of producing a collector with optimal ratio of fractions of light distillates, hydrocarbon oils, resin, and asphaltenes by mixing M-40 fuel oil with diesel fuel oil in specified ratios was substantiated. It was shown that applying compound collectors with M-40 fuel oil weight percentage of 60-70 enabled increasing diamond recovery by 2.7-3.5%. Similar increase was also achieved when using F-5 bunker fuel oil diluted by 10-18% with diesel oil fraction. The optimal temperature of 24 °C for initial ore feed conditioning with flotation agents and foam separation providing maximum diamond recovery into concentrate and high selectivity was determined. The proposed collectors and temperature conditions enabled increasing diamond recovery.
采用萃取-分光光度法测定了泡沫分离过程中高、低分子量组分固液相分布的定量和定性规律。通过将M-40燃料油与柴油按特定比例混合,生产出具有最佳比例的轻质馏分、烃类油、树脂和沥青质的捕集剂的可行性得到了证实。结果表明,采用M-40燃料油质量百分比为60-70的复合捕收剂,可使金刚石回收率提高2.7-3.5%。当使用含有10-18%柴油馏分的F-5船用燃料油时,也获得了类似的提高。确定了采用浮选剂和泡沫分离进行初始选矿的最佳温度为24℃,可获得最大的金刚石精矿回收率和高选择性。所提出的捕收剂和温度条件提高了金刚石的回收率。
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引用次数: 0
Evaluation of excavator energy consumption and overburden cutting resistance using multiple linear regression 利用多元线性回归评价挖掘机能耗和上覆土切割阻力
Pub Date : 2022-01-01 DOI: 10.5937/jmma2201039t
J. Trivan, S. Kostić
In present paper the energy consumption of the excavator and overburden linear cutting resistance by invoking the multiple linear regression was examined. As a result, the corresponding models as nonlinear functions of physical and mechanical overburden properties: grain size, unit weight, cohesion, and friction angle, were proposed. The analysis was based on records made at ''Tamnava Eastern Field'' mine for the bucket-wheel excavator with new excavation teeth. The obtained results indicated that excavator energy consumption significantly depended on the grain size and cohesion, as individual factors, while the effect of two-factor interactions was particularly significant: clay percentage with cohesion and small grained sand fraction, and friction angle with medium grained sand and cohesion. On the other hand, linear cutting resistance of the overburden was largely controlled by all the examined physical and mechanical properties (grain size, unit weight, and shear strength), with the following significant two-factors interactions: shear strength parameters with all grain size fractions, different grain size fractions among each other, and friction angle with unit weight.
本文采用多元线性回归法对挖掘机的能耗和覆盖层的线性切割阻力进行了研究。建立了覆盖层粒径、单位重量、黏聚力和摩擦角等物理力学特性的非线性函数模型。分析的依据是在“Tamnava东部矿区”对新开挖齿的斗轮挖掘机所做的记录。研究结果表明,挖掘机能耗对粒径和黏聚力的影响显著,对粘聚力和小粒砂掺量的粘土掺量、对中粒砂和黏聚力的摩擦角的影响尤为显著。另一方面,覆盖层的抗线切割性能在很大程度上受所检测的所有物理力学性能(粒径、单位重量和抗剪强度)的控制,并且存在以下显著的双因素交互作用:抗剪强度参数与所有粒径级、不同粒径级之间以及摩擦角与单位重量的交互作用。
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引用次数: 0
Intensification of diamond purification from hydrophilic minerals in foam separation process 泡沫分离过程中亲水矿物对金刚石提纯的强化作用
Pub Date : 2021-01-01 DOI: 10.5937/jmma2101019d
G. Dvoichenkova, V. Morozov, E. Kovalenko, Y. Podkamenny
The reason for diamond loss in foam separation process consists in the fact that the diamond crystals fed to the foam separation are coated with hydroxides and carbonates. A combined method to restore the diamond hydrophobicity through thermal and electrochemical destruction of the mineral coat was proposed. This method provides for the conditioning stage in the foam separation process to enable decreasing the amount of the minerals coating diamonds surface from 3 to 10 times. Technological research showed that using products of diaphragm less electrolysis of recirculating water, with the thermal treatment of the foam separation feed enables increasing the recovery of diamonds in the foam separation concentrate from 76.5% to 83.7%.
泡沫分离过程中金刚石损失的原因在于供泡沫分离的金刚石晶体被氢氧化物和碳酸盐包裹。提出了一种通过热破坏和电化学破坏矿物涂层来恢复金刚石疏水性的方法。该方法规定了泡沫分离过程中的调理阶段,使覆盖在钻石表面的矿物的数量从3到10倍减少。工艺研究表明,采用循环水无隔膜电解产品,配合泡沫分离料的热处理,可将泡沫分离精矿中金刚石的回收率从76.5%提高到83.7%。
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引用次数: 1
Implication of geological domains data for modeling and estimating resources from Nkout iron deposit (South-Cameroun) 南喀麦隆Nkout铁矿地质域数据对资源建模与估算的意义
Pub Date : 2021-01-01 DOI: 10.5937/jmma2101001b
A.W. Boroh, K.Y. Sore-Gamo, Ngounouno Ayiwouo, Mbowou Gbambie, I. Ngounouno
This paper is devoted to determining whether the addition of geological information can improve the resource estimate of mineral resources. The geochemical data used come from 116 drill holes in the Nkout East iron deposit in southern Cameroon. These geochemical data are modeled on Surpac and Isatis softwares to represent the 3D geochemical distribution of iron in the deposit. Statistical analysis and then a variographic study is performed to study the spatial variability of iron. Estimation domains were defined based on the results of geological and geochemical analyses. Four domains were determined. These domains are the saprolitic domain in particular; the poor domain or fresh rocks such as amphibolites, granites, and gneisses; the rich domain or oxidized rocks (BIF) and the metasediment domain. Block modeling of the deposit is performed to estimate the resource. The grade of each block was estimated by using ordinary kriging and composites from each domain. This study also consisted of comparing two types of estimate, notably the domain estimate and the global estimate. The cross-validation made it possible to authenticate the obtained models. From this comparison, the domain estimation brings more precision the global estimate precisely on the error analysis while if we take into account the point clouds of the predicted and estimated values, the estimation by geochemical modeling provides the best results.
本文致力于确定地质信息的加入是否能改善矿产资源的资源估计。所使用的地球化学数据来自喀麦隆南部Nkout东铁矿的116个钻孔。这些地球化学数据在Surpac和Isatis软件上进行建模,以表示矿床中铁的三维地球化学分布。通过统计分析和变差分析,研究了铁的空间变异性。根据地质和地球化学分析结果确定估算域。确定了四个域。这些结构域特别是腐殖岩结构域;贫域或角闪岩、花岗岩、片麻岩等新鲜岩石;富岩域或氧化岩域和沉积域。对矿床进行块建模以估计资源。利用普通克里格和各域的复合数据对各块的品位进行估计。本研究还包括比较两种类型的估计,特别是域估计和全局估计。交叉验证使得验证获得的模型成为可能。结果表明,在误差分析上,区域估计比全局估计更精确,而在考虑预测值和估计值的点云时,地球化学模拟估计的结果最好。
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引用次数: 1
Comparison of the influence of polyacrylamide and sodium oleate on selective flocculation of goethite from sludge 聚丙烯酰胺与油酸钠对污泥中针铁矿选择性絮凝效果的比较
Pub Date : 2021-01-01 DOI: 10.5937/jmma2101043t
Ljiljana Tankosić, S. Sredić
The paper represents a part of research conducted with the aim of examining the possibility of applying selective flocculation of goethite from sludge that occurs in the process of iron ore production. The aim of this study was to compare the influence of polyacrylamide and sodium oleate as a flocculant on the settling behavior of goethite under different conditions. The paper presents the results of the research on the influence of the flocculants based on polyacrylamide and sodium oleate, as well as pH values on the settling rate of a natural goethite sample. The results showed that the settling rate of goethite was influenced by pH value and the type of flocculant, while the concentration of flocculant did not significantly affect the settling rate. Measurements of zeta potential showed the effect of flocculants on the surface of the goethite.
本文是为了探讨对铁矿生产过程中产生的污泥进行选择性絮凝处理的可能性而进行的研究的一部分。本研究的目的是比较聚丙烯酰胺和油酸钠作为絮凝剂在不同条件下对针铁矿沉降行为的影响。本文研究了聚丙烯酰胺、油酸钠等絮凝剂及pH值对天然针铁矿沉降速率的影响。结果表明:针铁矿的沉降速率受pH值和絮凝剂种类的影响,而絮凝剂的浓度对沉降速率影响不显著。zeta电位的测定表明絮凝剂对针铁矿表面的影响。
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引用次数: 1
Effect of pyrolysis temperature on desulfurization performance of high organic sulfur low rank coal 热解温度对高有机硫低阶煤脱硫性能的影响
Pub Date : 2021-01-01 DOI: 10.5937/jmma2101027x
W. Xia, W. He, J. Sokolović
The sulfur in coal not only influences the coke quality but also pollutes the environment during the combustion. The desulfurization of high organic sulfur coal is a key issue in coal cleaning science. As the pyrolysis has been used in low-rank coal conversion to obtain gas/liquid products and coal char, the desulfurization effects of pyrolysis on the low-rank coal with high organic sulfur requires further studies. This study investigated the desulfurization performance of high organic sulfur low-rank coal by the pyrolysis and the changes in the coal calorific value and sulfur forms during the pyrolysis. The XPS was applied to analyze the changing regulation of sulfur that forms on coal surface. The results indicated certain amount of FeS was newly created during the pyrolysis and high amounts of sulfate sulfur was transferred to pyrite sulfur and formed more FeS2 when compared to the distribution of raw coal. The total sulfur content of coal was reduced from 2.32% for raw coal to 1.68% for 700 °C pyrolysis coal and then the pyrolysis temperature had little effect on the sulfur content. The net calorific value (at constant volume and air-dry basis) was increased from 17.38 kJ for raw coal to 24.35 kJ for 700 °C pyrolysis coal. The pyrolysis temperature of 700 °C may be the best pyrolysis temperature for both low sulfur content and high calorific value.
煤中的硫不仅影响焦炭的质量,而且在燃烧过程中还会污染环境。高有机硫煤的脱硫是洗煤科学中的一个关键问题。由于热解已在低阶煤转化中得到气/液产品和煤焦,因此热解对高有机硫低阶煤的脱硫效果有待进一步研究。研究了高有机硫低阶煤的热解脱硫性能,以及热解过程中煤的热值和硫形态的变化。利用XPS分析了煤表面硫的变化规律。结果表明,与原煤的分布相比,热解过程中产生了一定量的FeS,大量的硫酸盐硫向黄铁矿硫转移,形成了更多的FeS2。煤的总硫含量由原煤的2.32%降至700℃热解煤的1.68%,热解温度对硫含量影响不大。净热值(在等体积和风干基础上)从原煤的17.38 kJ增加到700℃热解煤的24.35 kJ。热解温度为700℃可能是低硫含量和高热值的最佳热解温度。
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引用次数: 0
Acid mine drainages from copper mines in the southeast Serbia: Local problem with an international impact 塞尔维亚东南部铜矿的酸性矿井排水:具有国际影响的地方问题
Pub Date : 2021-01-01 DOI: 10.5937/jmma2101033s
V. Stanković, D. Božić, M. Gorgievski, G. Bogdanović, M. Zikic
Through this study special attention was paid to AMDs, originating from copper mines, containing different heavy metal ions, and a certain amount of sulphuric acid. The research was conducted on the territory encompassing the RTB Bor mines (now Serbia Zijin Bor Copper). The AMDs occurrences, their water composition, metal potential, and impact on the local surface waters were determined. The major amount of mine waters flow into the Krivelj River damaging extremely its water quality. The research also included monitoring the Timok river water quality along its course from the Krivelj River inflow to the confluence with the Danube. Evaluating the metal losses, it was found that every year around 360 tons of copper, >500 tons of iron, and 30 tons of zinc from mine waters are lost, as being transported via the Krivelj River to the Timok and then to the Danube.
通过本研究,特别关注了产自铜矿、含有不同重金属离子和一定数量硫酸的矿渣。这项研究是在RTB博尔矿(现塞尔维亚紫金博尔铜矿)周围的领土上进行的。测定了AMDs的产状、水成分、金属电位及其对当地地表水的影响。矿井水大量流入克里维尔河,严重破坏了克里维尔河的水质。这项研究还包括监测从克里韦利河流入到多瑙河汇合处的Timok河的水质。对金属损失进行评估后发现,每年大约有360吨铜、500吨以上的铁和30吨锌从矿山水中流失,这些金属通过克里韦利河运往铁穆克河,然后再运往多瑙河。
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引用次数: 0
The impact of high-power electromagnetic pulses on the surface state and technological properties of the calciferous minerals 大功率电磁脉冲对钙化矿物表面状态和工艺性质的影响
Pub Date : 2019-01-01 DOI: 10.5937/jmma1901045c
V. Chanturiya, Bunin I. Zh, M. Ryazantseva
The modification of structural chemical properties of natural fluorite, scheelite and calcite under the impact of high-power electromagnetic pulses (HPEMP-treatment) were studied with help of adsorption of acid-base indicators. It was determined that the HPEMP-treatment during of 30 seconds (3 x 103 pulses) resulted in the intensification of fluorite surface 'electron-donating ability and acceptor properties of calcite and scheelite surfaces. Single mineral flotation tests has allowed to determine that treatment by high-power electromagnetic pulses resulted in the improvement of the calciferous minerals floatability. The rising of the scheelite recovery was 10 - 12%, for fluorite it was 5 - 6%, for calcite 7 - 8%.
通过对酸碱指示剂的吸附,研究了大功率电磁脉冲处理对天然萤石、白钨矿和方解石结构化学性质的影响。结果表明,30秒(3 × 103脉冲)的hppp处理增强了萤石表面的给电子能力,增强了方解石和白钨矿表面的受体性质。单矿物浮选试验表明,高功率电磁脉冲处理可改善钙化矿物的可浮性。白钨矿回收率提高10 ~ 12%,萤石回收率提高5 ~ 6%,方解石回收率提高7 ~ 8%。
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引用次数: 0
期刊
Journal of Mining and Metallurgy Section A Mining
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