The catalytic activity of manganese oxide catalysts for the toluene oxidation process

H. T. Tran, Chuc Van Nguyen, Thuy T B Ly, Quang Dinh Ta, H. T. Nguyen, Hung Manh Khong, Thang Minh Le
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Abstract

Manganese oxide catalysts were prepared by several preparation methods, such as hydrothermal, sol-gel method, and characterized by XRD, BET, H2-TPR, SEM-EDS, and FT-IR. The catalytic activities of catalysts were evaluated through the toluene reaction at the temperature range of 150 oC – 400 oC. Among the catalysts, the @ MnO2 150  catalyst exhibited the highest catalytic activity. It could completely convert toluene into CO2 at 300  oC. The larger specific surface area and lower reduction temperature enhance the higher activity of the @ MnO2 150 catalyst. Thus, the @ MnO2 150  catalyst is chosen to study in the subsequent research.
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锰氧化物催化剂对甲苯氧化过程的催化活性
采用水热法、溶胶-凝胶法等制备方法制备了锰氧化物催化剂,并用XRD、BET、H2-TPR、SEM-EDS和FT-IR对其进行了表征。通过在150℃~ 400℃范围内甲苯反应,评价了催化剂的催化活性。其中,@ mno2150催化剂的催化活性最高。它能在300℃时将甲苯完全转化为二氧化碳。较大的比表面积和较低的还原温度使@ mno2150催化剂具有较高的活性。因此,在后续的研究中选择了@ mno2150催化剂进行研究。
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