Solvates of the Fluorofullerenes C60F46 AND C60F48 with Aliphatic Hydrocarbons

P. Troshin, Y. Mackeyev, N. Chelovskaya, Y. Slovokhotov, O. Boltalina, L. Sidorov
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引用次数: 3

Abstract

Abstract The binary systems fluorofullerene - aliphatic hydrocarbon with normal structure were studied. The fluorofullerenes C60F48 and C60F48 were found to form molecular solvates with n-pentane, n-hexane, n-heptane, n-nonane, n-decane and n-undecane. Thermal gravimetry was used to estimate the mole composition of the solvates, differential scanning calorimetry - the dynamics of their decomposition and X-ray powder diffraction - the crystal structure of the solvates. The solubility of C60F48 in alkanes at room temperature was determined and dependence of solubility upon properties of solvates was shown.
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氟富勒烯C60F46和C60F48与脂肪烃的溶剂化物
摘要研究了正构氟富勒烯-脂肪烃二元体系。氟富勒烯C60F48和C60F48与正戊烷、正己烷、正庚烷、正壬烷、正癸烷和正十一烷形成分子溶剂。热重法测定了溶剂化物的摩尔组成,差示扫描量热法测定了溶剂化物的分解动力学,x射线粉末衍射测定了溶剂化物的晶体结构。在室温下测定了C60F48在烷烃中的溶解度,并指出了溶解度与溶剂化物性质的关系。
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