Phase Formation of M-Type BaFe12O19/ZnO Magnetic Material

S. Humaidi, T. Simbolon, D. Barus, Veryyon Hrp, S. Perdamean, K. Chandra, S. EkoArif, S. Silviana
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Abstract

High Energy Milling (HEM) followed by heat treatment was used to prepare M-type BaFe12O19/ZnO magnetic material in toluene media. High purity of BaFe12O19 and ZnO powder was milled for 12 h followed by drying for 4 h before being calcined at a temperature of 900C. The powder was then filtered by using T-200. An appropriate amount of BaFe12O19 and ZnO were then mixed in wet-milling for 15 mins and dried at 200C for 1 h. The magnetic properties were analysed using VSM, whereas the phase formation was derived from XRD-pattern (powder method) using X-ray CuKα 40kV-30mA with λ= 1.5418 Å. The phase occurrence was determined using MATCH-software program. It was obtained that BaFe12O19 lattice parameter: a = 5.8930 Å, c = 23.1940 Å. In order to get soft magnetic state, ZnO was added with a composition of: 0/100, 25/100, 50/100, 75/100, respectively. It was found that addition of 75% ZnO to BaFe12O19 converted hard magnet to soft magnet.
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m型BaFe12O19/ZnO磁性材料的相形成
在甲苯介质中,采用高能铣削(HEM) -热处理法制备m型BaFe12O19/ZnO磁性材料。将高纯度的BaFe12O19和ZnO粉末研磨12 h,干燥4 h,然后在900℃下煅烧。然后用T-200过滤粉末。然后将适量的BaFe12O19和ZnO混合湿磨15分钟,在200℃下干燥1小时。使用VSM分析磁性能,使用x射线CuKα 40kV-30mA (λ= 1.5418 Å)进行xrd图(粉末法)分析相形成。采用match软件程序确定相位发生。得到BaFe12O19晶格参数:a = 5.8930 Å, c = 23.1940 Å。为了获得软磁状态,分别以0/100、25/100、50/100、75/100的比例加入ZnO。结果表明,在BaFe12O19中加入75%的ZnO可使硬磁体转变为软磁体。
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