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Mechanical Properties and Morphology Biocomposites of Polycaprolactone (PCL)/Modified using Trisodium Trimetaphosphate 聚己内酯/三甲基磷酸三钠改性生物复合材料的力学性能和形态
Marpongahtun, C. F. Zuhra, S. Lenny, D. Nasution, M. Aulya, S. A. Amaturrahim, Mahmud, Fitria Puspa Dewi, Irmayani
: The determination of the mechanical properties and morphology of polycaprolactone (PCL) / breadfruit polytocyte biocomposites tied up with trisodium trimetaposphate was performed. The breadfruit starch is tied with trisodium trimetaposphate to produce pospat starch. The highest degree of substitution was obtained in variation of trisodium weight of trimetafosfat 3%, that is 0,0633. PCL / Starch Biocomposite was prepared by mixing method between PCL in chloroform solvent with modified 3% sodium starch then printed at 75˚C since 10 minutes. Mechanical properties, functional group, and morphological of PCL/Modified breadfruit starch biocomposite was analyzed. The result of evaluation showed an optimal tensile test value of 90%: 10% with tensile strenght of 7,4287 MPa and Modulus Young’s of 27,852 MPa. The functional group analysis of phosphate starch showed asymmetric P-O-C group at wave number 1018,41 cm -1 . Analysis with FT-IR from PCL/Modified Breadfruit Starch Biocomposite showed of physical interaction occurred between PCL and modified breadfruit starch. Morphological analysis using SEM showed smooth and homogeneous surface of biocomposite.
对聚己内酯(PCL) /面包果多细胞生物复合材料的力学性能和形态进行了测定。将面包果淀粉与三偏磷酸三钠结合生成后淀粉。当三氟化三甲醚的三钠质量变化3%时,取代度最高,为0,0633。将PCL与改性3%淀粉钠在氯仿溶剂中混合制备PCL / Starch生物复合材料,在75℃下打印10 min。对PCL/改性面包果淀粉生物复合材料的力学性能、官能团和形态进行了分析。评价结果表明,最佳拉伸试验值为90%:10%,拉伸强度为7,4287 MPa,杨氏模量为27,852 MPa。磷酸淀粉的官能团分析显示,在波数1018,41 cm -1处存在不对称P-O-C基团。对改性面包果淀粉与PCL生物复合材料的红外光谱分析表明,PCL与改性面包果淀粉之间存在物理相互作用。扫描电镜形态分析表明,复合材料表面光滑均匀。
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引用次数: 0
Quality Improvement of Liquid Smoke of Coconut Shell by Tar Scrubber 焦油洗涤器改善椰壳液烟品质
R. M. Sari, S. Gea, B. Wirjosentono, S. Hendrana
: One of the most challenging issues concerning to the pyrolysis of liquid smoke coconut shell is the presence of tar. The acidity, water content, density and content analysis of liquid smoke using coconut shell which produced at 500 o C using pyrolysis reactor equipped with a tar scrubber were compared to liquid smoke produced conventionally. Characterization of acidity of the liquid was measured by pH meter by adhering to ASTM E70, water content by using volumetric Karl Fischer titration method following ASTM E203 and ASTM D1744 method, the density by AOC 1995, and dichloromethane extracts content by gas chromatography-mass spectrometry (GC-MS). The results showed that the pH range of liquid smoke was pH 2.4 to 2.6 with the water content of 89.970 to 94.593%, and the density of 1.0118 to 1.0036 g/mL. The carbonyl and phenol content were 5.05 to 6.473% and 85.057 to 90.024% respectively. From the results can be concluded that the quality of liquid smoke produced by tar scrubber is better than the quality of liquid produced by conventional method.
关于液态烟椰壳热解的最具挑战性的问题之一是焦油的存在。对在500℃条件下,采用带焦油洗涤器的热解反应器生产的椰壳液烟的酸度、含水量、密度及含量分析进行了比较。按照ASTM E70标准用pH计测定酸度,按照ASTM E203和ASTM D1744标准用体积卡尔费休滴定法测定含水量,采用AOC 1995测定密度,采用气相色谱-质谱联用(GC-MS)测定二氯甲烷提取物含量。结果表明:液烟的pH范围为pH 2.4 ~ 2.6,含水量为89.970 ~ 94.593%,密度为1.0118 ~ 1.0036 g/mL。羰基含量为5.05 ~ 6.473%,苯酚含量为85.057 ~ 90.024%。结果表明,焦油洗涤器产生的烟液质量优于常规方法产生的烟液质量。
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引用次数: 1
Antimicrobial Properties of [2-(Acryloyloxy)Ethyl]-Trimethyl Ammonium Chloride and Maleic Anhydride Surface Grafted-Cotton Fibers [2-(丙烯氧基)乙基]-三甲基氯化铵和马来酸酐表面接枝棉纤维的抗菌性能
H. Sartiva
Antimicrobial compound of [2-(acryloyloxy)ethyl]-trimethyl ammonium chloride (AETAC) can be bound into polymer backbones to produce various antimicrobial polymeric materials. In this work, cotton cellulose (CCell) fibres was modified in a laboratory scale reflux-reactor for 2 hours in toluene (TL) as solvent with addition of maleic anhydride (MA). TL solution of antimicrobial compound of AETAC and ammoniumpersulphate (NH4)2S2O8) as initiator was added dropwise and the reflux was further continued for 2 hours. The reaction mixture with optimum weight ratio (CCell/MA/AETAC: 100/20/20) was then cooled down, filtered and wash thoroughly using distilled water and dried in oven vacum to constant weight at 80C. The AETAC/MA-modified Cellulose (AETAC/MA-g-CCell) was then characterised using infrared spectroscopy (FTIR) for chemical structure identification of the reaction products. Antimicrobial properties of the modified cellulose was tested using: Aspergillus niger and Staphylococcus aureus. Results of FTIR spectra of the AETAC/MA-g-CCell after exhaustive Soxhlet extraction in toluene still showed stable absorption peak of AETAC/MA carbonyl group (>C=O) at 1736 cm and dissapearance of bond absorption peak of acryloyl group (>C=C<) at 1470 cm. The AETAC/MA-modified cotton cellulose showed marginal antimicrobial activity against Aspergillus niger, however the modified cellulose showed excellent antimicrobial activity against Staphylococcus aureus.
抗菌化合物[2-(丙烯氧基)乙基]-三甲基氯化铵(AETAC)可以结合到聚合物骨架中,生产各种抗菌高分子材料。在这项工作中,棉花纤维素(CCell)纤维在实验室规模的回流反应器中以甲苯(TL)为溶剂,添加马来酸酐(MA),改性2小时。以AETAC抗菌复合物和过硫酸铵(NH4)2S2O8为引发剂,滴加TL溶液,继续回流2小时。将最佳质量比(CCell/MA/AETAC: 100/20/20)的反应混合物冷却,用蒸馏水过滤并彻底清洗,并在80℃烤箱真空干燥至恒重。利用红外光谱(FTIR)对AETAC/ ma改性纤维素(AETAC/ ma -g- cell)进行表征,对反应产物进行化学结构鉴定。用黑曲霉和金黄色葡萄球菌对改性纤维素的抗菌性能进行了测试。在甲苯中彻底索氏萃取后,AETAC/MA-g-电池的FTIR光谱显示,AETAC/MA羰基(>C= 0)在1736 cm处的吸收峰仍然稳定,丙烯基(>C=C<)的键吸收峰在1470 cm处消失。AETAC/ ma改性棉纤维素对黑曲霉的抑菌活性较弱,而对金黄色葡萄球菌的抑菌活性较好。
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引用次数: 0
Sustainable Supply Chain Management in Manufacture 制造业中的可持续供应链管理
N. Sembiring, M. Tambunan, E. Ginting, Intan Sari Dewi
: This paper introduces sustainable supply chains in the manufacturing industry, which include environmental, social and financial aspects and several variables that influence them. This paper contains a review of several studies on sustainable supply chains that have been carried out previously from 2005 to 2018. This paper begins with an introduction to sustainable supply chains and exposure to problems underlying the ongoing supply chain. Then the methodology and steps are explained. This paper objective is to afford a simple review of sustainable supply chain management (SSCM). The manufacturing industry is always related to chemical processes at the stages of the production process. This also always influences the environment. That is why the sustainable topic becomes an important thing to study and to find the solutions. In addition, conclusions and suggestions can be given to the supply chain of the manufacturing industry in the future.
本文介绍了制造业的可持续供应链,包括环境、社会和财务方面以及影响它们的几个变量。本文回顾了2005年至2018年间开展的几项关于可持续供应链的研究。本文首先介绍了可持续供应链和暴露于正在进行的供应链背后的问题。然后说明了方法和步骤。本文的目的是提供一个简单的回顾可持续供应链管理(SSCM)。制造业在生产过程的各个阶段总是与化学过程有关。这也会影响环境。这就是为什么可持续的话题成为一个重要的事情来研究和寻找解决方案。此外,还可以对未来制造业的供应链提出结论和建议。
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引用次数: 0
Synthesis 2-(3-Phenylallylidenamino) Pentanedioic Acid by Condensation of Cinnamaldehyde with Glutamic Acid and the Activity Test as Antibact 肉桂醛与谷氨酸缩合合成2-(3-苯丙烯氨基)戊二酸及其抗菌活性试验
M. Ginting
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引用次数: 0
Identifying Trends of Sustainable Supply Chain Management 确定可持续供应链管理的趋势
N. Sembiring, M. Tambunan, E. Ginting
: This paper discusses the role of sustainable supply chain management is still a new thing of manufacturing companies. This review papers of SSCM is done from period 2018-2019. From the results of the review it can be seen the trends of the sustainable supply chain model that could be used as a reference for future research. This study discusses the concepts that have been applied to previous studies of sustainable supply chains involving organizations, based on assessment and study of literature on supply chains. In this journal there are several parts, namely the first part which contains the research background. The second section contains a literature review that is the literature that supports research and about the results of a review of several research journals about SSCM from 2018 and 2019. The third section contains the methods used in the research, which contain the stages of research. The fourth part contains a summary of research, the results of research on SSCM. The manufacturing industry is always related to chemical processes at the stages of the production process. This also always influences the environment. That is why the sustainable topic becomes an important thing to study and to find the solutions.
本文论述了可持续供应链管理在制造业企业中的作用。本次SSCM综述论文的撰写时间为2018-2019年。从回顾的结果中可以看出可持续供应链模型的发展趋势,可以作为未来研究的参考。本研究在评估和研究供应链文献的基础上,讨论了以往涉及组织的可持续供应链研究中应用的概念。本刊分为几个部分,第一部分为研究背景。第二部分包含文献综述,即支持研究的文献以及2018年和2019年关于SSCM的几份研究期刊的综述结果。第三部分是研究中使用的方法,包含了研究的各个阶段。第四部分是本文的研究总结,是对企业供应链管理的研究成果。制造业在生产过程的各个阶段总是与化学过程有关。这也会影响环境。这就是为什么可持续的话题成为一个重要的事情来研究和寻找解决方案。
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引用次数: 0
Analysis of Physical Properties and Chemical Contents in Eucalyptus citriodora PT. Toba Pulp Lestari, Tbk 柠檬桉(Eucalyptus citriodora PT. Toba Pulp Lestari, Tbk)理化性质分析
Z. Alfian, M. Taufik, S. Lenny, Chintya Cahaya, R. Hidayati, Simon Sidabuke, E. Manullang, Jeremi Sitohang
: Eucalyptus citriodora is one type of eucalyptus that has the potential to be developed. This plant originates from Australia, which is one of the most popular eucalyptus trees that grows in almost all of Australia, and is now found to grow in almost all tropical regions of the world including Indonesia. Content Analysis and determination of sineol Content in Eucalyptus citriodora leaf essential oil from PT. Toba Pulp Lestari Tbk has been carried out by the GCMS method. Eucalyptus leaves have been used for medicine, industry and perfume as well as Eucalyptus oil. The purpose of this study was to determine the compound content and levels of cineol in Eucalyptus citriodora leaves. The abundance of sineol levels 55-65% can be used as perfume, medicines and Eucalyptus oil. Stahl distillation was developed to produce The Eucalyptus oil. There are eleven compounds in Eucalyptus citriodora leaves, including α-Pinene, 1-Limone, 1.5 Cyclooctadiene, 1.8 Sineol, 1-P-Menthen-8-YL-Acetate, 3- Cycloheksane, 1-Methanol, α-Terpinyl Acetate, Phenol, Butylhidroxytoluena, Trans-Methyl-dihydrojasmonate, ISO - Cytronellate, ISO - Propyl Myristat, Propyltetradekanoate, Octadecanoic Acid. The mximum abundance is 1,8-cineol (60.29% v/v). The physical properties was obtained used titrimetric method yields of acidity and ester numbers respectively 2.8025 and 12.0 (T= 26.010C).
柑橘桉是一种极具开发潜力的桉树。这种植物原产于澳大利亚,是最受欢迎的桉树之一,几乎生长在澳大利亚的所有地区,现在发现它生长在世界上几乎所有的热带地区,包括印度尼西亚。采用气相色谱法测定了托巴纸浆(PT. Toba Pulp Lestari Tbk)中柠檬酸桉叶精油的含量。桉树的叶子被用于医药、工业和香水以及桉树油。本研究的目的是测定柠檬桉叶中桉叶油酚的含量和含量。辛油酸含量55-65%,可用作香水、药品和桉树油。斯塔尔蒸馏是用来生产桉树油的。柠檬桉叶中含有α-蒎烯、1-柠檬酮、1.5环己二烯、1.8辛油醇、1- p - menth -8- yl- Acetate、3- Cycloheksane、1-Methanol、α-Terpinyl Acetate、苯酚、Butylhidroxytoluena、Trans-Methyl-dihydrojasmonate、ISO - Cytronellate、ISO - Propyl Myristat、Propyltetradekanoate、Octadecanoic Acid等11种化合物。最大丰度为1,8-桉叶油醇(60.29% v/v)。用滴定法测定了其物理性质,酸度和酯值分别为2.8025和12.0 (T= 26.010C)。
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引用次数: 0
X-Ray Diffraction and Morphology Studies of Sulfonated Polystyrene and Maleated Natural Rubber Blend with PE-g-MA as Compatibilished 以PE-g-MA为配伍剂的磺化聚苯乙烯和马来化天然橡胶共混物的x射线衍射和形貌研究
A. Pulungan, B. Wirjosentono, Eddiyanto, S. Hendrana
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引用次数: 1
In Vitro Investigation of Bacterial Cellulose/Turmeric Extract (BC-TE) Nanocomposite for Burn Wound Dressing 细菌纤维素/姜黄提取物(BC-TE)纳米复合材料烧伤创面敷料的体外研究
Rio Cahyono Siahaan, Melati Sitorus, R. Mulia, S. Gea
: Bacterial cellulose is an interesting polymer material for using as a wound dressing. Bacterial cellulose has an excellent physical and chemical properties such as high biocompatibility, microporosity, transparant, non-toxic, and also it provides moist environment that made this polymer ideal for wound dressing. However, bacterial cellulose itself has no antimicrobial activity to prevent wound infection. To achieve antimicrobial activity, turmeric extract (TE) were impregnated into bacterial cellulose by immersing bacterial cellulose (BC) in turmeric extract solution to produce BC-TE nanocomposite. A scanning electron microscope (SEM) was used to examine the surface morphology of BC and BC–TE nanocomposite. Antimicrobial tests in vitro indicated that BC–TE nanocomposite showed excellent antibacterial activity against Staphylococcus aureus , and Escherichia coli with the inhibition zone of 12.45 mm and 10 mm, respectively
细菌纤维素是一种有趣的高分子材料,可用作伤口敷料。细菌纤维素具有高生物相容性、微孔性、透明、无毒等优异的物理化学性能,并能提供湿润的环境,是理想的伤口敷料。然而,细菌纤维素本身没有抗菌活性来防止伤口感染。以姜黄提取物(TE)为研究对象,将细菌纤维素(BC)浸泡在姜黄提取物溶液中,制备BC-TE纳米复合材料。采用扫描电镜(SEM)对BC和BC - te纳米复合材料的表面形貌进行了观察。体外抑菌试验表明,BC-TE纳米复合材料对金黄色葡萄球菌和大肠杆菌具有良好的抑菌活性,抑菌范围分别为12.45 mm和10 mm
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引用次数: 0
Analysis of Total Phenolics and Flavonoid from the Root Bark of Flacourtia rukam 黄皮根皮中总酚类和类黄酮的分析
Muharni, Elfita, Julinar, H. Yohandini
Flacourtia rukam have been used in the to folk medicine. The roots was used by women after giving birth as antiseptic and the stem bark was used to antihypertensive in the Regency of Musi Banyu Asin South Sumatera Indonesia. Total phenolic and flavonoid content were determined for methanol, ethyl acetate and n-hexane extracts from the root bark of F. rukam. Each extracts were determined antioxidant activity using 1,1-diphenyl-2-picryl-hydrazyl (DPPH) method. The results of the study showed that phenolic higher in methanol extract (71.8868 mg GAE/g) compared with ethyl acetate extract (56.6094 mg GAE/g), while nhexane extract no detection. For flavonoids content showed, methanol extract (2.3116 mg QE/g) and ethyl acetate extract (2.3304 mg QE/g) where the flavonoid content is not significantly different, while n-hexane extract only contained flavonoid 0.8129 mg QE/g. The antioxidant activity the methanol, and ethyl acetate extracts showed IC50 52.91μg/mL and 86.92 μg/mL and in categorized as active antioxidant, while n-hexane extract obtained IC50 values 268.02 μg/ml in category weak antioxidant.
黄花已被用于民间医学。在印度尼西亚南苏门答腊的Musi Banyu Asin摄政时期,妇女在分娩后使用根作为防腐剂,茎皮用于降压。测定了甘露根皮甲醇、乙酸乙酯和正己烷提取物中总酚和类黄酮的含量。采用1,1-二苯基-2-苦基-肼(DPPH)法测定各提取物的抗氧化活性。研究结果表明,甲醇提取物的酚类含量(71.8868 mg GAE/g)高于乙酸乙酯提取物(56.6094 mg GAE/g),而正己烷提取物无检出。总黄酮含量方面,甲醇提取物(2.3116 mg QE/g)和乙酸乙酯提取物(2.3304 mg QE/g)的总黄酮含量差异不显著,而正己烷提取物的总黄酮含量仅为0.8129 mg QE/g。甲醇和乙酸乙酯提取物的IC50值分别为52.91和86.92 μg/mL,属于活性抗氧化剂;正己烷提取物的IC50值为268.02 μg/mL,属于弱抗氧化剂。
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引用次数: 0
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Proceedings of the 1st International Conference on Chemical Science and Technology Innovation
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