Effects of SiO2 particles on surface charge of epoxy nanocomposites

B. Du, Li Wang, J. Zhang, Yong Liu, Y. Gao
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引用次数: 4

Abstract

Epoxy used as insulating material in electronic and electrical devices plays an important role in system reliability. Addition of nanoparticles into epoxy can improve the insulating properties compared with undoped material. However, due to the change of the material structure, trap characteristics and charge behaviors are altered as a consequence. This possibly leads to a great risk of electric field distortion and discharge that degrades the insulation. From the viewpoint of safety, it is necessary to investigate the charge behavior on epoxy nanocomposites. This paper presents study aimed at clarifying the effect of nano-filler content on surface charge accumulation and decay behaviors of epoxy nanocomposites with SiO2 particles. Samples were prepared by dispersing nano-scale SiO2 into epoxy by mixing with shear force. Corona charging tests were performed at room temperature with a relative humidity of ~ 40%. The charge distribution was measured by means of an electrostatic voltmeter. Obtained results show the dependence of the accumulated charge as well as the charge decay rate upon the concentration of SiO2, varying as a function of the charge polarity, charging time and charging voltage. It is suggested that the charge dynamics is dependent upon the characteristics of localized surface states that are altered by the nanoparticles.
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SiO2颗粒对环氧纳米复合材料表面电荷的影响
环氧树脂作为电子电气设备的绝缘材料,对系统的可靠性起着重要的作用。与未掺杂的材料相比,在环氧树脂中加入纳米颗粒可以改善其绝缘性能。然而,由于材料结构的改变,导致了陷阱特性和电荷行为的改变。这可能会导致电场畸变和放电的巨大风险,从而降低绝缘。从安全的角度出发,有必要研究环氧纳米复合材料的电荷行为。本文旨在阐明纳米填料含量对含SiO2环氧纳米复合材料表面电荷积累和衰减行为的影响。用剪切力将纳米级SiO2分散到环氧树脂中制备样品。电晕充电试验在室温下进行,相对湿度为~ 40%。电荷分布是用静电伏特计测量的。实验结果表明,累积电荷和电荷衰减率随SiO2浓度的变化而变化,随电荷极性、充电时间和充电电压的变化而变化。结果表明,电荷动力学取决于纳米粒子改变的局部表面态的特性。
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