Evaluation of Health Risk from Concentrations of Heavy Metal in PM-10 and PM-2.5 particles at Sasang Industrial Complex of Busan, Korea

Seong-Hwa Choi, Seong-Woo Choi, Dong-Yeong Kim, Y. Cha, Seung-Woo Park, Seoi Lee, Eun-chul Yoo
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Abstract

We investigated the distribution of hazardous heavy metals (As, Cr6+, Ni, Cd, Pb, and Mn) and estimated the health risk related to the heavy metals in fine dust (PM-10 and PM-2.5) of Sasang industrial complex, Busan, Korea. The concentration of fine dust in the industrial complex was 1.2 times higher than in a residential area, while harmful heavy metals showed a difference of at least 1.3 times (Cd) and up to 6.5 times (Ni). The concentration of fine dust and carcinogenic heavy metals in the industrial complex increased significantly compared to the residential area in spring (March to May) and winter (December to February) months. A risk assessment was performed using Monte-Carlo simulations containing a four-step procedure. During hazard identification, As, Cr6+ Ni, Cd, and Pb were categorized as human carcinogens and probable human carcinogens and evaluated for their levels of excess cancer risk. For concentrations of over 90% Cr6+ and As, the excess cancer risk was over 10-5 (1 person per 100,000). The non-cancer hazard index of As, Cr6+, Cd, and Mn was below the limit value of 1.
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釜山沙上工业园区PM-10和PM-2.5中重金属浓度的健康风险评价
我们调查了有害重金属(As, Cr6+, Ni, Cd, Pb和Mn)的分布,并估计了与韩国釜山沙上工业园区细尘中重金属(PM-10和PM-2.5)相关的健康风险。工业园区的微细颗粒物浓度是居住地区的1.2倍,有害重金属(Cd)的浓度是1.3倍以上,Ni的浓度是6.5倍以上。在春季(3 ~ 5月)和冬季(12 ~ 2月),工业园区内的微细颗粒物和致癌物质的重金属浓度明显高于居民区。使用蒙特卡罗模拟进行风险评估,其中包含四步程序。在危害识别过程中,As、Cr6+ Ni、Cd和Pb被归类为人类致癌物和可能的人类致癌物,并评估了它们的过量致癌风险水平。对于浓度超过90%的Cr6+和As,癌症风险超过10-5(每10万人中有1人)。As、Cr6+、Cd、Mn的非癌危害指数均低于1的极限值。
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