Influence of Temperature Annealing on Structural and Substructural Properties of Heterojunction ZnO / Cu2ZnSnS4 Obtained by Spraying Nanoinks

Maksym Yermakov, O. Dobrozhan, S. Kakherskyi, R. Pshenychnyi, A. Opanasyuk
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Abstract

In this work, a multilayer structure was obtained using ZnO and Cu2 ZnSnS4 (CZTS) inks on a molybdenum substrate by spraying. The obtained samples were annealed in Argon for 10 and 60 min at temperatures of 250°C, 450°C and 550°C. Structural and substructural characteristics were studied by X-ray diffraction. Due to this, the influence of temperature and annealing time on the sizes of coherent scattering regions (CSR), the level of microdeformations and the lattice parameters of the obtained samples were investigated. Based on the study, the optimal annealing conditions in Argon were determined to obtain multilayer structures using ZnO and Cu2ZnSnS4 materials for use in solar energy.
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温度退火对喷涂纳米油墨制备的ZnO / Cu2ZnSnS4异质结结构和亚结构性能的影响
本文利用ZnO和Cu2 ZnSnS4 (CZTS)油墨在钼基板上喷涂制备了多层结构。将得到的样品在250℃、450℃和550℃的氩气中退火10和60 min。通过x射线衍射研究了其结构和亚结构特征。因此,研究了温度和退火时间对样品的相干散射区(CSR)大小、微变形水平和晶格参数的影响。在此基础上,确定了ZnO和Cu2ZnSnS4材料在氩气中的最佳退火条件,以获得用于太阳能的多层结构。
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