Dependence on supermolecular structure and on charge injection conditions of ferroelectric switching of PVDF and its blends with PMMA

A. Becker, M. Stein, B. Jungnickel
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引用次数: 8

Abstract

PVDF is a semicrystalline polymer with very interesting ferroelectric, pyroelectric and piezoelectric properties. It is the aim of the present paper to prove the importance of the amorphous phase for the strength of the respective activity coefficients. To this end, the structure and the dynamics of this particular phase is varied by blending with PMMA and by suitable annealing. It will be shown that the electric efficiency is governed to a large extent by the type, the number, the mobility, and the properties of trapping sites of injected charges which migrate through, and reside in, the amorphous phase.
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PVDF及其与PMMA共混物铁电开关的超分子结构及电荷注入条件的依赖性
PVDF是一种半结晶聚合物,具有非常有趣的铁电性、热释电性和压电性。本文的目的是证明非晶相对各自活度系数强度的重要性。为此,通过与PMMA共混和适当的退火来改变该特定相的结构和动力学。结果表明,电效率在很大程度上取决于注入电荷的类型、数量、迁移率和捕获点的性质,这些电荷通过非晶相迁移并驻留在非晶相中。
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