Evaluation of Temperature Dependency of Gas Permeability on Various Kinds of Elastomers

Yasutaka Yamada, S. Sogo
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引用次数: 2

Abstract

Gas permeation test equipment was developed to measure the gas permeability through O-ring shape elastomers under actual condition of semiconductor manufacturing such as high vacuum and high temperature. The temperature dependencies of gas permeability on three kinds of elastomers, silicone (VMQ), ‰uoroelastomer (FKM) and per‰uoroelastomer (FFKM), were investigated. Permeation rate for all materials increased as temperature increased. O2 and N2 gas permeation rate through VMQ was much higher than that through the other materials, especially in lower temperature. Moreover, the temperature dependencies of gas permeability with VMQ were completely diŠerent from those of FKM and FFKM. This was coming from diŠerent polymer structure which caused diŠerence of solubility and diŠusivity between silicon and ‰uoroelastomers.
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不同弹性体透气性对温度依赖性的评价
研制了在高真空、高温等半导体制造实际条件下测量o形弹性体透气性的气体渗透性测试装置。研究了有机硅(VMQ)、‰‰弹性体(FKM)和‰‰‰弹性体(FFKM)三种弹性体对透气性的温度依赖性。随着温度的升高,所有材料的渗透速率都增加。O2和N2气体通过VMQ的渗透速率远高于其他材料,特别是在较低温度下。VMQ对透气性的温度依赖性与FKM和FFKM完全diŠerent相同。这是由于diŠerent聚合物结构导致硅和硅弹性体之间的溶解度diŠerence和diŠusivity。
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