V. V. Eremkin, V. Smotrakov, L.E. Balyunis, S. I. Shevtsova, A. Kozakov
{"title":"Phase T,x-diagram of Pb/sub 1-x/Ca/sub x/TiO/sub 3/ single crystals","authors":"V. V. Eremkin, V. Smotrakov, L.E. Balyunis, S. I. Shevtsova, A. Kozakov","doi":"10.1109/ISAF.1994.522307","DOIUrl":null,"url":null,"abstract":"Phase T,x-diagram of the Pb/sub 1-x/Ca/sub x/TiO/sub 3/ (0/spl les/x/spl les/0.62) solid solution system has been constructed in the range from room temperature to 770 K using data of single crystal optical studies and X-ray microanalysis. Besides the typical for PbTiO/sub 3/ ferroelectric tetragonal and paraelectric cubic phases, two ferro- and non-ferroelectric ones having the pseudomonoclinic unit cell distortions also as two additional tetragonal phases, at least one of which is confidently non-ferroelectric, have been found and their exact stability limits have been determined.","PeriodicalId":20488,"journal":{"name":"Proceedings of 1994 IEEE International Symposium on Applications of Ferroelectrics","volume":"1 1","pages":"97-100"},"PeriodicalIF":0.0000,"publicationDate":"1994-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Proceedings of 1994 IEEE International Symposium on Applications of Ferroelectrics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/ISAF.1994.522307","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Phase T,x-diagram of the Pb/sub 1-x/Ca/sub x/TiO/sub 3/ (0/spl les/x/spl les/0.62) solid solution system has been constructed in the range from room temperature to 770 K using data of single crystal optical studies and X-ray microanalysis. Besides the typical for PbTiO/sub 3/ ferroelectric tetragonal and paraelectric cubic phases, two ferro- and non-ferroelectric ones having the pseudomonoclinic unit cell distortions also as two additional tetragonal phases, at least one of which is confidently non-ferroelectric, have been found and their exact stability limits have been determined.