Fabrication of Nanocomposite Adsorbent Based on MnO2-loaded Polymer Fibers for Strontium Ions

Yu.V. Bondar, S. Kuzenko, Yu. A. Olkhovyk
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Abstract

Novel nanocomposite adsorbent based on manganese dioxide-loaded polyacylonitrile propylene fibers was synthesized for selective removal of strontium ions from contaminated waters by in situ formation of manganese dioxide with layered structure (birnessite) nanoparticles on the fibers surface. Data of scanning electron microscopy and X-ray diffraction confirmed the formation of birnessite homogeneous layer on the fibers surface, which consisted of rounded nanoparticles (50 to 70 nm). The efficiency of the synthesized adsorbent for removal of strontium ions was studied under various experimental conditions. It has demonstrated a rapid adsorption process, high adsorption efficiency over a wide pH range, and selectivity in Sr ions removal from model solutions with high salt content.
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基于二氧化锰负载聚合物纤维的锶离子纳米复合吸附剂的制备
合成了一种新型二氧化锰负载型聚丙烯腈-丙烯纤维纳米复合吸附剂,通过在纤维表面原位形成具有层状结构的二氧化锰(birnite)纳米颗粒来选择性去除污染水中的锶离子。扫描电镜和x射线衍射数据证实,纤维表面形成了一层由圆形纳米颗粒(50 ~ 70 nm)组成的birnite均质层。在不同的实验条件下,研究了合成的吸附剂对锶离子的去除效果。它具有快速的吸附过程,在较宽的pH范围内具有较高的吸附效率,并且在高含盐量的模型溶液中具有选择性去除Sr离子。
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