New approach for High Reliable & Cost-Effective Solder alloys for Automotive Applications

S. Fritzsche, Manu Noe Vaidya, P. Prenosil, Katja Stenger, Jörg Trodler, M. Jörger
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Abstract

Commercially known as Innolot, the highly reliable lead-free alloy, allowing for high operating temperatures, is a Tin-Silver-Copper (SAC) metallurgical system with additional elements to harden the alloy and to improve its creep strength in order to significantly improve the reliability of solder joints. Compared to traditional SAC alloys, the characteristic lifetime can be enhanced on the base of temperature cycle tests (TCT) from −40°C to +125°C or even extended to 150°C. Assemblies in the automotive industry increasingly require higher reliability for safety relevant and emerging applications such as Advanced Driver Assistance Systems (ADAS). Cost-reduction requirements demand a new approach for optimized soldering processes and materials. As the current reflow process prefers Nitrogen atmosphere for low defects in high reliability soldering, our research focuses around the partial and/or complete change to air soldering processes. Furthermore, we investigate the influence of different surface finishes such as Chemical Sn, NiAu, and Cu OSP, and modified alloy compositions in the soldering performance. Apart from initial characterizations for various assemblies, reliability tests on Heraeus Reliability1 printed circuit boards as well as temperature cycle tests from −40 to +150°C for up to 2500 cycles are reported and resulting failure modes are discussed. This paper furthermore describes the potential for cost reductions via process and/or material optimizations without diminishing the high reliability performance for such automotive applications.
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高可靠性和高成本效益的汽车焊料合金的新方法
商业上被称为Innolot,高度可靠的无铅合金,允许高工作温度,是锡银铜(SAC)冶金系统,具有额外的元素来硬化合金并提高其蠕变强度,以显着提高焊点的可靠性。与传统SAC合金相比,在温度循环测试(TCT)的基础上,其特征寿命可以从- 40°C提高到+125°C,甚至延长到150°C。汽车行业的组件越来越需要更高的可靠性,以满足与安全相关的新兴应用,如高级驾驶辅助系统(ADAS)。降低成本的要求需要优化焊接工艺和材料的新方法。由于目前的回流工艺在高可靠性焊接中更倾向于氮气气氛,因此我们的研究重点是部分和/或完全改变空气焊接工艺。此外,我们还研究了不同表面处理(如化学Sn、NiAu和Cu OSP)以及改性合金成分对焊接性能的影响。除了各种组件的初始特性外,还报告了贺利氏可靠性1印刷电路板的可靠性测试以及从- 40°C到+150°C长达2500个循环的温度循环测试,并讨论了由此产生的故障模式。本文进一步描述了通过工艺和/或材料优化来降低成本的潜力,而不会降低此类汽车应用的高可靠性性能。
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