Thermostimulated luminescence and photoluminescence of microcrystalline zinc sulphide ZnS:Cu

S. Kutovyy, О. Stanovyi
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Abstract

In the work, photoluminescence (PL) and thermoluminescence (TL) spectra of a zinc sulfide phosphor series, namely microcrystalline ZnS:Cu obtained by self-propagating high-temperature synthesis (SHS), were obtained and analyzed. Based on the spectral analysis, the character of the influence of annealing parameters on the intensity of the “blue” (B) and “green” (G) PL bands is established. The behaviors of the PL and TL bands are compared and the TL bands in the blue and green spectral regions are identified. The TL mechanism was assumed to be the specific nature of the centers that cause the B- and G-bands of PL.
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微晶硫化锌ZnS:Cu的热激发发光和光致发光
本文对自传播高温合成(SHS)法制备的硫化锌荧光粉系列微晶ZnS:Cu的光致发光(PL)和热致发光(TL)光谱进行了分析。在光谱分析的基础上,建立了退火参数对“蓝”(B)和“绿”(G)光强的影响特征。比较了PL波段和TL波段的行为,确定了蓝、绿光谱区的TL波段。TL机制被认为是引起PL的B和g波段的中心的特定性质。
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