Lead (II) Nitrate Catalyzed Esterification Palmitic Acid with Alcohols

N. Bangun, J. Karo-karo, H. Nainggolan, S. Silaban, Nia Erisa Tarigan, Rahmad Ramadan
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Abstract

Esters has been long known in some applications that has been attempted to prepare in many fashion methods. Several catalysts used based on acid either solid or liquid has been known popular. A transition salt also has been intensively reported catalyzes esterification. Very few catalysts from Group A metal shown activities esterification catalysis. Lead (II) nitrate shown a good catalyst performance in esterification long chain fatty acid reacts with primary and secondary alcohol. Palmitic acid reacts with alcohols, glycerol, 1,2-propane diol as well as stearyl alcohol gives high yield ester respectively. All ester has been characterized in FT-IR, 1H NMR and 13C NMR spectrophotometer shown the yield was 90-97%.
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硝酸铅催化棕榈酸与醇的酯化反应
酯类化合物在一些应用中早已为人所知,并已尝试以多种方法制备。几种基于酸性固体或液体的催化剂已被广泛使用。一种过渡盐也被广泛报道催化酯化反应。很少有A族金属催化剂具有酯化催化活性。硝酸铅(II)在长链脂肪酸与伯、仲醇酯化反应中表现出良好的催化性能。棕榈酸分别与醇、甘油、1,2-丙烷二醇和硬脂醇反应生成高收率酯。经FT-IR、1H NMR和13C NMR表征,所得酯收率为90-97%。
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