M. Popov, S. Zazhigalov, T. Larina, S. Cherepanova, A. Bannov, S. Lopatin, A. Zagoruiko
{"title":"Glass fiber supports modified by layers of silica and carbon nanofibers","authors":"M. Popov, S. Zazhigalov, T. Larina, S. Cherepanova, A. Bannov, S. Lopatin, A. Zagoruiko","doi":"10.1515/cse-2017-0001","DOIUrl":null,"url":null,"abstract":"Abstract The new multi-layered composite was manufactured by deposition of the carbon nanofibers (CNF) at the surface of the glass-fiber fabric, which is pre-modified by application of additional external layers of NiO and porous silica. Carbonization of synthesized catalytic template was performed at 450 °C in propanebutane media at ambient pressure. CNF was deposited in amount of ~130% of initial template mass or 65 g per g of nickel, the specific surface area of the material is ~100 m2/g. The synthesized material has high mechanical strength, high hydrophobicity and strong bonding between CNF and glass-fiber support. The synthesis method is technologically simple, inexpensive and easily scalable. It is possible to manufacture such material in various solid shapes, using the flexibility of the primary glass-fiber support; in particular, it may be used for production of the mechanically self-sustainable catalytic cartridges with required shape and internal geometry using no additional structuring elements.","PeriodicalId":9642,"journal":{"name":"Catalysis for Sustainable Energy","volume":"64 1","pages":"1 - 6"},"PeriodicalIF":0.0000,"publicationDate":"2017-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis for Sustainable Energy","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1515/cse-2017-0001","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 3
Abstract
Abstract The new multi-layered composite was manufactured by deposition of the carbon nanofibers (CNF) at the surface of the glass-fiber fabric, which is pre-modified by application of additional external layers of NiO and porous silica. Carbonization of synthesized catalytic template was performed at 450 °C in propanebutane media at ambient pressure. CNF was deposited in amount of ~130% of initial template mass or 65 g per g of nickel, the specific surface area of the material is ~100 m2/g. The synthesized material has high mechanical strength, high hydrophobicity and strong bonding between CNF and glass-fiber support. The synthesis method is technologically simple, inexpensive and easily scalable. It is possible to manufacture such material in various solid shapes, using the flexibility of the primary glass-fiber support; in particular, it may be used for production of the mechanically self-sustainable catalytic cartridges with required shape and internal geometry using no additional structuring elements.
摘要将纳米碳纤维(CNF)沉积在玻璃纤维织物表面,并在其表面添加NiO和多孔二氧化硅进行预改性,制备了新型多层复合材料。合成的催化模板在450℃的环境压力下,在丙丁烷介质中炭化。CNF沉积量为初始模板质量的~130%或65 g /g镍,材料的比表面积为~100 m2/g。该合成材料具有机械强度高、疏水性好、CNF与玻璃纤维支架之间结合强等特点。该合成方法技术简单,价格低廉,易于扩展。利用原始玻璃纤维支撑的灵活性,可以制造各种固体形状的这种材料;特别是,它可以用于生产具有所需形状和内部几何形状的机械自我可持续的催化筒,无需额外的结构元件。