Removal of Congo Red Dye Using Ficus benghalensis-Assisted Copper Oxide Nanoparticles

Tayyaba Shabir, Wardah Hassan, N. Abbas, Fakhar-un-Nisa, M. N. Akhtar, Zobia Yaseen, A. Yaseen, A. Ihsan, Mariam Khan
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Abstract

Novel water purification technologies are emerging to satisfy the requirement of clean drinking water for human life. The development of long-term water treatment systems is a serious concern. In this regard, nanotechnology holds enormous promise for improving the effectiveness and efficiency of polluted water remediation. The goal of this work was to create a simple and effective water purification system that used cost-effective, durable, and environmentally friendly novel materials. Green nanoparticle synthesis has emerged as a result of recent advancements in environmentally friendly technologies. The use of plant extract to synthesize nanoparticles is thought to be an incredible green strategy. In the present study, leaf extract of Ficus benghalensis was chosen to synthesize the low cost and novel copper oxide (CuO) nanoparticles. The aim was to investigate the ability of these novel nano particles in removing Congo red dye from water. Various parameters including contact time, adsorbent dosage, initial dye concentration and pH of dye solution that affect the adsorption were optimized by carrying out batch adsorption experiments. The mechanism of pseudo-first-order, pseudo-second-order, Langmuir equilibrium isotherm, and Freundlich isotherm was investigated using kinetic and equilibrium experimental data. These models gave an insight into the adsorption kinetics and adsorption mechanism. The pH effect revealed that Congo red dye being an acidic dye showed good adsorption at acidic pH.  The findings of this work show that copper oxide nanoparticles are promising adsorbents for the removal of Congo red dye from aqueous based system.
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榕树辅助氧化铜纳米颗粒去除刚果红染料
为了满足人类生活对清洁饮用水的需求,新型的水净化技术不断涌现。长期水处理系统的发展是一个严重的问题。在这方面,纳米技术在提高水污染修复的有效性和效率方面具有巨大的前景。这项工作的目标是创造一个简单而有效的水净化系统,使用成本效益高,耐用,环保的新型材料。绿色纳米颗粒的合成是最近环境友好技术进步的结果。利用植物提取物合成纳米粒子被认为是一种不可思议的绿色策略。本研究以榕叶提取物为原料,合成了低成本的新型氧化铜纳米颗粒。其目的是研究这些新型纳米颗粒从水中去除刚果红染料的能力。通过批量吸附实验,对接触时间、吸附剂用量、染料初始浓度、染料溶液pH等影响吸附的参数进行了优化。利用动力学和平衡实验数据研究了拟一阶、拟二阶、Langmuir平衡等温线和Freundlich等温线的机理。这些模型揭示了吸附动力学和吸附机理。pH效应表明刚果红染料是一种酸性染料,在酸性pH下具有良好的吸附性能。研究结果表明,氧化铜纳米颗粒是一种很有前途的吸附剂,可用于去除水基体系中的刚果红染料。
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