Additives in Polyvinyl Chloride and Polyvinylidene Chloride Products

Y. Kawamura, Chieko Tagai, Tamae Maehara, Takashi Yamada
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引用次数: 40

Abstract

The residue of 89 kinds of additives including plasticizers in polyvinyl chloride (PVC) and polyvinylidene chloride (PVDC) products were investigated. PVC wrapping films contained 14-38% of plasticizers, most of which were adipates, especially diisononyl adipate. However, few additives were observed in PVC containers. PVC gloves contained 34-55% of plasticizers, mostly di-2-ethylhexyl phthalate and di-2-ethylhexyl adipate, in all samples. The levels of plasticizers in toys were 8.7-45%, consisting mainly of diisononyl phthalate and di-2-ethylhexyl phthalate. On the other hand, the levels of plasticizers in PVDC wrapping films were only 2.7-7.8% (O-acetyl tributyl citrate and dibutyl sebacate). Nonylphenol was found in some PVC wrapping films, gloves and toys at concentrations of about 530-5, 500μg/g sample.
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聚氯乙烯和聚偏氯乙烯产品中的添加剂
研究了包括增塑剂在内的89种添加剂在聚氯乙烯(PVC)和聚氯乙烯(PVDC)制品中的残留情况。PVC保鲜膜中增塑剂的含量为14-38%,增塑剂以己二酸酯居多,尤以己二酸二异壬酯居多。然而,在PVC容器中很少观察到添加剂。在所有样品中,PVC手套含有34-55%的增塑剂,主要是邻苯二甲酸二-2-乙基己基酯和己酸二-2-乙基己基酯。玩具中增塑剂的含量为8.7-45%,主要包括邻苯二甲酸二异壬酯和邻苯二甲酸二-2-乙基己酯。增塑剂(柠檬酸o -乙酰三丁酯和癸酸二丁酯)的含量仅为2.7 ~ 7.8%。在部分PVC包装薄膜、手套和玩具中检测到壬基酚浓度约为530- 5500 μg/g。
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