Removal of Hydrogen Sulphide Gas Using Agricultural Wastes

T. Wajima
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Abstract

In Japan, the total generation of biomass waste is 300 million tons annually, and the shortage of the final disposal site is a problem. Therefore, new use of agricultural waste is required. A representative gas for odor damage is hydrogen sulphide gas. In this study, removal capacity of agricultural wastes for low concentration hydrogen sulphide gas was examined to use as hydrogen sulphide gas absorbent. Adsorption experiments on hydrogen sulphide gas (500 ppm) using peanut shell, rice straw, rice husk, and commercial charcoal were carried out. Experimental results showed that the adsorption amount of charcoal was 2335 mg/g, while those of agricultural wastes are very low (rice husk: 27 mg/g, peanut shell: 22 mg/g, rice straw: 18 mg/g). By pyrolyzing peanut shell, the H2S gas adsorption of peanuts shell promote with increasing pyrolysis temperature due to the high specific surface area, and its adsorption amount of the product pyrolyzed at 600 o C is about 65% of charcoal.
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利用农业废弃物去除硫化氢气体
在日本,每年产生的生物质废物总量为3亿吨,最终处置场地的短缺是一个问题。因此,需要对农业废弃物进行新的利用。气味损害的典型气体是硫化氢气体。本研究考察了农业废弃物对低浓度硫化氢气体的去除能力,并将其作为硫化氢气体的吸收剂。以花生壳、稻草、稻壳和商品炭为吸附材料,对500 ppm硫化氢气体进行了吸附实验。实验结果表明,活性炭的吸附量为2335 mg/g,而农业废弃物的吸附量很低(稻壳:27 mg/g,花生壳:22 mg/g,稻草:18 mg/g)。通过热解花生壳,由于花生壳的高比表面积,随着热解温度的升高,花生壳对H2S气体的吸附有所促进,其对600℃热解产物的吸附量约为木炭的65%。
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