A Review: Square Wave Adsorptive Stripping Voltammetry Determination ofPesticide and Ultra-trace Inorganic Ions in Environmental Samples

Dereje Fedasa, Alemu Talema, Shuma Fayera
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Abstract

Environmental pollution caused by pesticides and ultra-trace amounts of inorganic ions in the different environmental samples has become an issue of serious concern in the last years. Thus, the development of novel, simple, fast, sensitive, and cheap methods for the detection of pesticide residues and ultra-trace inorganic ions in the environmental sample is very significant task now days. The SWAdSV can be conjuncted with different modified electrode such as SWAdSV with modified Hanging mercury drop electrode, SWAdSV with multi-walled carbon nanotube paste electrode, SWAdSV with boron-doped diamond electrode, SWAdSV with flow-injection analysis detection and etc. SWAdSV can be used to perform an experiment much faster than normal and differential pulse techniques, which typically run at scan rates of 1 to 10 mV/sec. Square wave voltammetry employs scan rates up to 1 V/sec or faster, allowing much faster determinations. A typical experiment requiring three minutes by normal or differential pulse techniques can be performed in a matter of seconds by square wave voltammetry. The aim of the review was the use of square wave adsorptive stripping voltammetry in conjunction with different modified electrode for the determination of pesticide and ultra-trace inorganic ions in environmental samples.
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方波吸附溶出伏安法测定环境样品中农药和超微量无机离子的研究进展
近年来,农药和不同环境样品中超微量无机离子对环境的污染已成为人们严重关注的问题。因此,开发一种新颖、简单、快速、灵敏、廉价的检测环境样品中农药残留和超微量无机离子的方法是当前非常重要的任务。SWAdSV可以与不同的修饰电极结合使用,如:修饰挂汞电极的SWAdSV、多壁碳纳米管膏状电极的SWAdSV、掺硼金刚石电极的SWAdSV、流动注射分析检测的SWAdSV等。SWAdSV可以比普通脉冲和差分脉冲技术更快地进行实验,后者通常以1到10 mV/秒的扫描速率运行。方波伏安法采用扫描速率高达1 V/秒或更快,允许更快的测定。用常规或差分脉冲技术需要三分钟的典型实验,用方波伏安法几秒钟就能完成。本文综述了方波吸附溶出伏安法结合不同修饰电极对环境样品中农药和超微量无机离子的测定。
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