{"title":"The spectra and structure of aluminium chloride complexes. Part IV. Structure of higher complexes of aluminium chloride","authors":"D. E. Jones, J. Wood","doi":"10.1039/J19710003135","DOIUrl":null,"url":null,"abstract":"The complexes AlCl3,2Me2O,AlCl3,1·5MeCN, AlCl3,2MeCN, and AlCl31·5HCO2Me have been examined by i.r. and Raman spectroscopy; model calculations support a trigonal-bipyramidal five-co-ordinate structure for AlCl3,2Me2O but ionic structures are suggested for the others. AlCl3,2MeCN has uncombined MeCN in the crystal lattice.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710003135","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 3
Abstract
The complexes AlCl3,2Me2O,AlCl3,1·5MeCN, AlCl3,2MeCN, and AlCl31·5HCO2Me have been examined by i.r. and Raman spectroscopy; model calculations support a trigonal-bipyramidal five-co-ordinate structure for AlCl3,2Me2O but ionic structures are suggested for the others. AlCl3,2MeCN has uncombined MeCN in the crystal lattice.
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