Studying the properties of polypyrrole-montmorillonite polyacrylic-urethane nanocomposite coatings: the role of an eco-friendly ionic liquid

R. Amini, P. Kardar
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Abstract

Purpose This paper aims to achieve an anti-corrosive coating via uniform dispersion of nanoclay particles (montmorillonite) and polypyrrole (PPy) as a conductive polymer as well as their effects on the anti-corrosion features in the presence of the eco-friendly ionic liquids (ILs). Design/methodology/approach In this research, PPy with different forms of nanoclay were used. Moreover, ILs additive is used to enhance the better dispersion process of clay and PPy nanoparticles in the resin. Findings As a result, the IL additive in the formulation of nano-composite coatings greatly improves the dispersion process of clay and PPy nanoparticles in the resin. Due to its high compatibility with polyurethane resin and clay and PPy nanoparticles, this additive contains a high dispersing power to disperse the investigated nanoparticles in the resin matrix. Research limitations/implications High polarity of ILs as well as abilities to dissolve both mineral and organic materials, they can provide the better chemical processes compared to common solvents. Practical implications IL abilities have not been discovered to a large extent such as catalysts and detectors. Social implications ILs have been emerging as promising green solvents to replace conventional solvents in recent years. They possess unique properties such as nonvolatility, low toxicity, ease of handling, nonflammability and high ionic conductivity. Thus, they have received much attention as green media for various chemistry processes. Originality/value The simultaneous existence of clay, PPy and IL additive in the nano-composite coating formulation is responsible for the high corrosion resistance of the coating.
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聚吡咯-蒙脱土-丙烯酸-聚氨酯纳米复合涂料的性能研究:环保离子液体的作用
目的研究纳米粘土颗粒(蒙脱土)和导电聚合物聚吡咯(PPy)在生态友好型离子液体(ILs)存在下均匀分散的防腐涂层及其对防腐性能的影响。设计/方法/方法在本研究中,使用了不同形式的纳米粘土的PPy。此外,还添加了ILs,增强了粘土和PPy纳米颗粒在树脂中的分散效果。结果表明,在纳米复合涂料配方中加入白介素添加剂,大大改善了粘土和聚吡啶纳米颗粒在树脂中的分散过程。由于其与聚氨酯树脂、粘土和聚吡啶纳米颗粒的高度相容性,该添加剂具有很高的分散能力,可以分散所研究的纳米颗粒在树脂基体中。研究局限/启示:与普通溶剂相比,il的高极性以及溶解矿物和有机材料的能力可以提供更好的化学过程。实际意义在很大程度上还没有发现硅的能力,如催化剂和探测器。近年来,sils已成为替代传统溶剂的有前途的绿色溶剂。它们具有不挥发性、低毒性、易于处理、不可燃性和高离子导电性等独特性能。因此,它们作为各种化学过程的绿色介质受到了广泛的关注。纳米复合涂层配方中粘土、PPy和IL添加剂的同时存在是涂层具有高耐腐蚀性的原因。
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