Investigation of Lignosulphonate Mannich Bases as Corrosion Inhibitors

Hua-rui Hao, Yanqing Miao
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Abstract

To seek for new acidic corrosion inhibitor, this work used aliphatic amine, formaldehyde and sodium lignosulphonate as the raw materials to prepare new Mannich bases as eco-friendly corrosion inhibitors. The inhibition of these Mannich bases for mild steel corrosion in 2M HCl solution was investigated by weight loss technique. Through the single factor experiments, the optimal mole ratio was determined. Meanwhile, the influences of temperature and inhibitor dosage on the corrosion inhibition performance of the products were studied. The adsorptions on the surface of mild steel and inhibition mechanism were also discussed. Potentiodynamic polarization studies indicate that extracts are mixed-type inhibitors.
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木质素磺酸曼尼希碱缓蚀剂的研究
为了寻找新的酸性缓蚀剂,本文以脂肪胺、甲醛和木质素磺酸钠为原料,制备了新型环保型曼尼希碱缓蚀剂。用失重法研究了这些曼尼希碱在2M HCl溶液中对低碳钢的缓蚀作用。通过单因素实验,确定了最佳摩尔比。同时,研究了温度和缓蚀剂用量对产物缓蚀性能的影响。并对其在低碳钢表面的吸附和缓蚀机理进行了讨论。动电位极化研究表明,提取物为混合型抑制剂。
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